Advances in catalytic asymmetric dearomatization

C Zheng, SL You - ACS Central Science, 2021 - ACS Publications
Asymmetric catalysis has been recognized as the most enabling strategy for accessing
chiral molecules in enantioenriched forms. Catalytic asymmetric dearomatization is an …

Complete field guide to asymmetric BINOL-phosphate derived Brønsted acid and metal catalysis: history and classification by mode of activation; Brønsted acidity …

D Parmar, E Sugiono, S Raja, M Rueping - Chemical reviews, 2014 - ACS Publications
The activation of a substrate by a chiral catalyst is now regarded as one of the most powerful
strategies that can be employed in the art of asymmetric synthesis. 1 The development of …

Catalytic asymmetric dearomatization reactions

CX Zhuo, W Zhang, SL You - … Chemie International Edition, 2012 - Wiley Online Library
This Review summarizes the development of catalytic asymmetric dearomatization (CADA)
reactions. The CADA reactions discussed herein include oxidative dearomatization …

Dearomatization strategies in the synthesis of complex natural products

SP Roche, JA Porco Jr - Angewandte Chemie International …, 2011 - Wiley Online Library
Evolution in the field of the total synthesis of natural products has led to exciting
developments over the last decade. Numerous chemoselective and enantioselective …

Additive effects on asymmetric catalysis

L Hong, W Sun, D Yang, G Li, R Wang - Chemical Reviews, 2016 - ACS Publications
This review highlights a number of additives that can be used to make asymmetric reactions
perfect. Without changing other reaction conditions, simply adding additives can lead to …

Asymmetric organocatalytic cyclization and cycloaddition reactions

A Moyano, R Rios - Chemical Reviews, 2011 - ACS Publications
The stereocontrolled construction of chiral carbo-and heterocycles is a topic of paramount
importance in modern organic synthesis, driven by the predominance of chiral mono-and …

Asymmetric dearomatization of phenols

W Sun, G Li, L Hong, R Wang - Organic & Biomolecular Chemistry, 2016 - pubs.rsc.org
This review summarizes the recent advances in the field of asymmetric dearomatization of
phenols and their applications in the total synthesis of some complex natural products. The …

Recent advances in asymmetric organocatalysis mediated by bifunctional amine–thioureas bearing multiple hydrogen-bonding donors

X Fang, CJ Wang - Chemical Communications, 2015 - pubs.rsc.org
Organocatalysis has proven to be one of the most rapidly developing and competitive
research areas in asymmetric catalysis since 2000, and has become a third branch besides …

Chiral Brønsted acids in enantioselective carbonyl activations–activation modes and applications

M Rueping, A Kuenkel, I Atodiresei - Chemical Society Reviews, 2011 - pubs.rsc.org
Chiral phosphoric acids and derivatives have attracted considerable attention as a powerful
tool in asymmetric catalysis. Various enantioselective reactions have been developed by …

Recent developments in the field of oxa-Michael reactions

CF Nising, S Bräse - Chemical Society Reviews, 2012 - pubs.rsc.org
Oxa-Michael reactions, ie addition reactions of oxygen nucleophiles to conjugated systems,
have traditionally received much less attention from the scientific community compared to …