Authenticating products and documents with security inks is vital to global commerce, security and health. Lanthanide complexes are widely used in luminescent security inks …
Lanthanide (III) luminescence is very characteristic: it is characterized by narrow emission bands, large Stokes shift, and a long excited state lifetime. Moreover, chiral lanthanide …
R Carr, NH Evans, D Parker - Chemical Society Reviews, 2012 - pubs.rsc.org
Optical probes that provide information about local chirality have been developed based on changes to the circular polarisation of emitted light. Highly emissive complexes of lanthanide …
HC Aspinall - Chemical reviews, 2002 - ACS Publications
The classical examples of chirality in coordination chemistry are transition-metal chelate complexes of the type [M (bidentate) 3] that exist in nonsuperimposable mirror image forms …
G Muller - Dalton Transactions, 2009 - pubs.rsc.org
This perspective gives an introduction into the design of luminescent lanthanide (III)- containing complexes possessing chiral properties and used to probe biological materials …
Control of molecular chirality is central to contemporary chemistry, biology, and materials- related areas. Chiral photochemistry employs molecular and supramolecular chiral …
Circular polarization of luminescence is a phenomenon that can be observed for chiral molecules in isotropic solution, for molecular aggregates and molecular materials. Also, the …
Circular polarisation luminescence (CPL) emission spectroscopy is a powerful tool for probing the fundamental chiroptical features of optically emissive chiral molecular systems …
Y Nagata, T Nishikawa, M Suginome - Chemical Communications, 2014 - pubs.rsc.org
Poly (quinoxaline-2, 3-diyl) s containing (S)-2-methylbutoxy side chains were found to exhibit blue circularly polarized luminescence (CPL). The handedness of the CPL could be …