Intramolecular Tricarbonyl‐Ene Reactions and α‐Hydroxy‐β‐Diketone Rearrangements Inspired by the Biosynthesis of Polycyclic Polyprenylated Acylphloroglucinols
Structurally unique natural products pose biosynthetic puzzles whose solution can inspire
new chemical reactions. Herein, we propose a unified biosynthetic pathway towards some …
new chemical reactions. Herein, we propose a unified biosynthetic pathway towards some …
Bioinspired Total Synthesis of Hyperireflexolides A and B
Hyperireflexolides A and B were synthesized in six steps via the dearomatization and
fragmentation of a simple acylphloroglucinol starting material. The dearomatized …
fragmentation of a simple acylphloroglucinol starting material. The dearomatized …