Reduction of nitro compounds using 3d-non-noble metal catalysts

D Formenti, F Ferretti, FK Scharnagl, M Beller - Chemical reviews, 2018 - ACS Publications
The reduction of nitro compounds to the corresponding amines is one of the most utilized
catalytic processes in the fine and bulk chemical industry. The latest development of …

Mesoionic and related less heteroatom-stabilized N-heterocyclic carbene complexes: synthesis, catalysis, and other applications

A Vivancos, C Segarra, M Albrecht - Chemical reviews, 2018 - ACS Publications
Mesoionic carbenes are a subclass of the family of N-heterocyclic carbenes that generally
feature less heteroatom stabilization of the carbenic carbon and hence impart specific donor …

Stable abnormal N-heterocyclic carbenes and their applications

SC Sau, PK Hota, SK Mandal, M Soleilhavoup… - Chemical Society …, 2020 - pubs.rsc.org
Although N-heterocyclic carbenes (NHCs) have been known as ligands for organometallic
complexes since the 1960s, these carbenes did not attract considerable attention until …

Metal-free, rapid, and highly chemoselective reduction of aromatic nitro compounds at room temperature

M Jang, T Lim, BY Park, MS Han - The Journal of Organic …, 2022 - ACS Publications
In this study, we developed a metal-free and highly chemoselective method for the reduction
of aromatic nitro compounds. This reduction was performed using tetrahydroxydiboron [B2 …

PCP pincer carbene nickel (II) chloride, hydride, and thiolate complexes: hydrosilylation of aldehyde, ketone, and nitroarene by the thiolate complex

A Kumar, R Gupta, G Mani - Organometallics, 2023 - ACS Publications
The one-pot reaction between ethylenediamine, paraformaldehyde, and Ph2PH or t Bu2PH
gave a new diphosphine compound 1, 3-bis ((diphenylphosphaneyl) methyl) imidazolidine …

Reduction of nitroarenes catalyzed by microgel-stabilized silver nanoparticles

R Begum, ZH Farooqi, AH Aboo, E Ahmed… - Journal of hazardous …, 2019 - Elsevier
Abstract Poly (N-isopropylacrylamide-co-acrylamide)(PNA-BIS-2) microgels were
synthesized by free radical precipitation polymerization in aqueous medium. Spherical Ag …

Manganese-Catalyzed Chemoselective Hydrosilylation of Nitroarenes: Sustainable Route to Aromatic Amines

RR Behera, S Panda, R Ghosh, AA Kumar… - Organic Letters, 2022 - ACS Publications
Herein we report efficient catalytic hydrosilylations of nitroarenes to form the corresponding
aromatic amines using a well-defined manganese (II)–NNO pincer complex with a low …

Porous silica-encapsulated and magnetically recoverable Rh NPs: a highly efficient, stable and green catalyst for catalytic transfer hydrogenation with “slow-release” …

J Zhou, Y Li, H Sun, Z Tang, L Qi, L Liu, Y Ai, S Li… - Green …, 2017 - pubs.rsc.org
A core–shell structured nanocatalyst (Fe3O4@ SiO2-NH2-RhNPs@ mSiO2) that is
encapsulated with porous silica has been designed and prepared for catalyzing the transfer …

Biogenic synthesis of gold nanoparticles on a green support as a reusable catalyst for the hydrogenation of nitroarene and quinoline

S Adeyeye Nafiu, S Shaheen Shah… - Chemistry–An Asian …, 2021 - Wiley Online Library
Direct attachment of gold nanoparticles to a green support without the use of an external
reducing agent and using it for removing toxic pollutants from wastewater, ie, reduction of …

Synthesis of triazolylidene nickel complexes and their catalytic application in selective aldehyde hydrosilylation

Y Wei, SX Liu, H Mueller-Bunz, M Albrecht - ACS Catalysis, 2016 - ACS Publications
A set of nickel (II) Cp complexes with triazolylidenes containing various different wingtip
groups (aryl, alkyl, pyridyl, CH2OH) have been synthesized by direct metalation of the …