In situ Raman and in situ XRD analysis of PdO reduction and Pd° oxidation supported on γ-Al 2 O 3 catalyst under different atmospheres

A Baylet, P Marécot, D Duprez, P Castellazzi… - Physical Chemistry …, 2011 - pubs.rsc.org
Reduction of Pd° and decomposition of palladium oxide supported on γ-alumina were
studied at atmospheric pressure under different atmospheres (H2, CH4, He) over a 4 wt …

Double enhancement of hydrogen storage capacity of Pd nanoparticles by 20 at% replacement with Ir; systematic control of hydrogen storage in Pd–M nanoparticles …

H Kobayashi, M Yamauchi, R Ikeda, T Yamamoto… - Chemical …, 2018 - pubs.rsc.org
We report on binary solid-solution nanoparticles (NPs) composed of Pd and Ir, which are not
miscible at the equilibrium state of the bulk, for the first time, by means of a process of …

Hydrogen absorption in 1 nm Pd clusters confined in MIL-101 (Cr)

A Malouche, G Blanita, D Lupu, J Bourgon… - Journal of Materials …, 2017 - pubs.rsc.org
We report here the unprecedented modification of the hydrogen absorption/desorption
properties of 1 nm Pd clusters relative to the bulk and nanoparticles down to 2–3 nm. These …

Study of isotope effect on dehydrogenation kinetics of Pd based alloys using differential scanning calorimetry

A Sharma, D Rawat, SK Raut, RA Jat… - International Journal of …, 2022 - Elsevier
Owing to the large hydrogen isotope effect, palladium and palladium based alloy are of
great technological importance for their application in separation of hydrogen isotopes. The …

Catalytic pyrolysis of aliphatic carboxylic acids into symmetric ketones over ceria-based catalysts: Kinetics, isotope effect and mechanism

T Kulik, B Palianytsia, M Larsson - Catalysts, 2020 - mdpi.com
Ketonization is a promising way for upgrading bio-derived carboxylic acids from pyrolysis
bio-oils, waste oils, and fats to produce high value-added chemicals and biofuels. Therefore …

Laser-Stimulated Desorption of Hydrogen in Palladium for Dynamic Hydrogen Sorption Microanalysis

A Borgschulte, D Bleiner - Analytical Chemistry, 2024 - ACS Publications
Hydrogen is a volatile element, both as a molecular gas and as atomic hydrogen in
materials. A method is described for the detection of the corresponding dynamic hydrogen in …

The oil bath thermal cycling absorption process design and separation process research

L Deng, C Chen, G Huang, Y Shi, Y Yao, J Hu… - International Journal of …, 2023 - Elsevier
Thermal cycling absorption process (TCAP) has been developed for years to support the
separation of hydrogen isotopes, which has the characteristics of high separation efficiency …

Reaction pathways for hydrogen desorption from magnesium hydride/hydroxide composites: bulk and interface effects

F Leardini, JR Ares, J Bodega, JF Fernandez… - Physical Chemistry …, 2010 - pubs.rsc.org
This manuscript investigates the thermal desorption behaviour of MgH2/Mg (OH) 2
composites by means of thermal desorption spectroscopy. Besides the H2O and H2 …

Microstructure and hydrogen storage properties of MgH2–TiB2–SiC composites

I Milanović, S Milošević, Ž Rašković-Lovre… - Ceramics …, 2013 - Elsevier
The influence of TiB2 and SiC ceramics on H-desorption kinetics from MgH2 based
composites was investigated and correlated with the microstructure and morphology of the …

Hydrogen isotope effect on thermodynamic and kinetic properties of Pd based ternary alloys: Pd–Ag-M (M= Au, Zr)

SG Sawant, A Sharma, A Dutta, KV Ravikanth… - International Journal of …, 2024 - Elsevier
Owing to the importance of hydrogen and its isotopes in energy sector, the present study
investigates thermodynamic and kinetic hydrogen isotope effects on desorption reaction of …