Electronic structure of corrole derivatives: insights from molecular structures, spectroscopy, electrochemistry, and quantum chemical calculations

A Ghosh - Chemical Reviews, 2017 - ACS Publications
Presented herein is a comprehensive account of the electronic structure of corrole
derivatives. Our knowledge in this area derives from a broad range of methods, including UV …

Strategies for corrole functionalization

JFB Barata, MGPMS Neves, MAF Faustino… - Chemical …, 2017 - ACS Publications
This review covers the functionalization reactions of meso-arylcorroles, both at the inner
core, as well as the peripheral positions of the macrocycle. Experimental details for the …

Effect of extended π conjugation on the spectroscopic and electrochemical properties of boron difluoride formazanate complexes

SM Barbon, VN Staroverov… - The Journal of Organic …, 2015 - ACS Publications
The effect of extended π conjugation on the spectroscopic and electrochemical properties of
boron difluoride (BF2) formazanate complexes was studied by the systematic comparison of …

Synthesis and properties of boron porphyrinoids

A Sinha, T Chatterjee, M Ravikanth - Coordination Chemistry Reviews, 2022 - Elsevier
Boron being a small atom, its coordination chemistry with different porphyrinoids is very
unique and unusual compared to coordination chemistry of porphyrinoids with transition …

A new fundamental type of conformational isomerism

PJ Canfield, IM Blake, ZL Cai, IJ Luck, E Krausz… - Nature …, 2018 - nature.com
Isomerism is a fundamental chemical concept, reflecting the fact that the arrangement of
atoms in a molecular entity has a profound influence on its chemical and physical properties …

Minding our P-block and Q-bands: paving inroads into main group corrole research to help instil broader potential

W Lee, X Zhan, J Palma, J Vestfrid, Z Gross… - Chemical …, 2021 - pubs.rsc.org
Main group chemistry is often considered less “dynamic” than transition metal (TM)
chemistry because of predictable VSEPR-based central atom geometries, relatively slower …

NIR-emissive iridium (III) corrole complexes as efficient singlet oxygen sensitizers

W Sinha, L Ravotto, P Ceroni, S Kar - Dalton Transactions, 2015 - pubs.rsc.org
Three new iridium (III) corrole complexes, having symmetrically and asymmetrically
substituted corrole frameworks and judiciously varied axial ligands are prepared and …

Phenanthrene‐Embedded Carbaporphyrinoids and Related Systems: From Ligands to Cages and Molecular Switches

B Szyszko - European Journal of Organic Chemistry, 2022 - Wiley Online Library
This Review discusses the recent developments in the field of synthetic chemistry of PAH–
porphyrin hybrids, emphasizing phenanthrene‐embedded carbaporphyrinoids and related …

Aromaticity control via modifications of a macrocyclic frame: 5, 6-dimethoxyphenanthriporphyrin and 5, 6-dioxophenanthriporphyrin

K Kupietz, MJ Białek, A Białońska, B Szyszko… - Organic Chemistry …, 2018 - pubs.rsc.org
The incorporation of a 9, 10-dimethoxyphenanthrene moiety into a porphyrin framework
results in the formation of a hybrid macrocycle–5, 6-dimethoxyphenanthriporphyrin 1, fusing …

B–O–B bridged BOPPY derivatives: synthesis, structures, and acid-catalyzed cis–trans isomeric interconversion

S Wang, Z Wang, W Song, H Gao, F Wu, Y Zhao… - Dalton …, 2022 - pubs.rsc.org
A new class of BOPPY derivatives has been facilely synthesized by a two-step reaction of
coupling 3, 5-dimethylpyrrole-2-carbaldehyde with 2, 3-dihydrazinoquinoxaline (QDH) …