Heteroatom‐containing polymers have strong potential as sustainable replacements for
petrochemicals, show controllable monomer–polymer equilibria and properties spanning …

Since 2016, when simple triethylborane (Et3B) was revealed as a very capable catalyst for
the copolymerization of epoxides and carbon dioxide, research effort regarding this type of …

There is an ever-increasing demand for higher-performing polymeric materials
counterbalanced by the need for sustainability throughout the life cycle. Copolymers …

Polymers constructed from copolymerizations of carbohydrates with C1 feedstocks are
promising targets that provide transformation of sustainably sourced building blocks into …

In the quest for sustainable development, degradable polymers are attractive alternatives to
traditional fossil-based plastics. As monocomponent degradable polymers often suffer from …

Synchronously and thoroughly adjusting the chemical structure difference between two
blocks of the diblock copolymer is very useful for designing materials but difficult to achieve …

The synthesis of well-defined block copolymers from a mixture of monomers without
additional actions (“one-pot/one-step”) is an ideal and industrially valuable method. In …

The scientific community has witnessed extensive developments and applications of
organoboron compounds as synthetic elements and metal-free catalysts for the construction …

The direct copolymerization of p‐tosyl isocyanate (TSI) with epoxides, initiated by onium
salts in the presence of trialkylborane, to produce polyurethanes is reported. The rate of …

Herein, a remarkable conjugated bis‐guanidinate (CBG) supported zinc hydride,[{LZnH} 2;
L={(ArHN)(ArN)− C= N− C=(NAr)(NHAr); Ar= 2, 6‐Et2‐C6H3}](I) catalyzed partial reduction …