Metal–organic frameworks based on group 3 and 4 metals

L Feng, J Pang, P She, JL Li, JS Qin, DY Du… - Advanced …, 2020 - Wiley Online Library
Metal–organic frameworks (MOFs) based on group 3 and 4 metals are considered as the
most promising MOFs for varying practical applications including water adsorption, carbon …

Half‐integer spin triangles: old dogs, new tricks

AK Boudalis - Chemistry–A European Journal, 2021 - Wiley Online Library
Spin triangles, that is, triangular complexes of half‐integer spins, are the oldest molecular
nanomagnets (MNMs). Their magnetic properties have been studied long before molecular …

A perfect triangular dysprosium single-molecule magnet with virtually antiparallel Ising-like anisotropy

G Lu, Y Liu, W Deng, GZ Huang, YC Chen… - Inorganic Chemistry …, 2020 - pubs.rsc.org
We report a trinuclear dysprosium single-molecule magnet,[Dy3 (μ3-CO3)(Clbbpen)
3](CF3SO3)· 6MeCN, which has a perfectly equilateral triangular structure. The Ising-like …

Enhancing magnetic relaxation through subcomponent self-assembly from a Dy 2 to Dy 4 grid

XL Li, Z Ma, J Wu, Q Zhou, J Tang - Dalton Transactions, 2022 - pubs.rsc.org
The subcomponent self-assembly of 4, 6-dihydrazinopyrimidine and o-vanillin/
salicylaldehyde with different DyIII salts leads to the formation of Dy2 (1–3) and grid-like Dy4 …

Slow magnetic relaxation in a Dy 3 triangle and a bistriangular Dy 6 cluster

W Wang, T Shang, J Wang, BL Yao, LC Li, Y Ma… - Dalton …, 2022 - pubs.rsc.org
Two lanthanide single-molecule magnets (SMMs)[Dy3 (μ3-OH)(HL-1) 3 (H2O) 3](NO3) 2·
3H3O (1, H3L-1=(E)-3-(((8-hydroxyquinolin-2-yl) methylene) amino) propane-1, 2-diol) and …

Tuning the Ferrotoroidic Coupling and Magnetic Hysteresis in Double‐Triangle Complexes {Dy3MIIIDy3} via the MIII‐linker

JM Ashtree, I Borilović, KR Vignesh… - European Journal of …, 2021 - Wiley Online Library
We present the syntheses, structures, magnetic data and theoretical analyses for two
families of heptanuclear clusters, wherein two staggered dysprosium (III) triangles are linked …

The Role of Magnetic Dipole—Dipole Coupling in Quantum Single-Molecule Toroics

K Hymas, A Soncini - Magnetochemistry, 2022 - mdpi.com
For single-molecule toroics (SMTs) based on noncollinear Ising spins, intramolecular
magnetic dipole–dipole coupling favours a head-to-tail vortex arrangement of the semi …

Studies of decoherence in strongly anisotropic spin triangles with toroidal or general noncollinear easy axes

K Irländer, J Schnack - Physical Review Research, 2023 - APS
Magnetic molecules are investigated with respect to their usability as units in future quantum
devices. In view of quantum computing, a necessary prerequisite is a long coherence time of …

Toroidal magnetic molecules stripped to their basics

D Pister, K Irländer, D Westerbeck, J Schnack - Physical Review Research, 2022 - APS
Molecular magnetic toroidal moments are molecule-based structures of quantum spins that
are expected to boost magnetic storage technology and quantum computing. We study …

Building Molecular Nanomagnets by Encapsulating Lanthanide Ions in Boron Nitride Nanotubes: Ab Initio Investigation

D Liu, X Guo, X Zhang, AA Al-Kahtani… - Inorganic …, 2024 - ACS Publications
Lanthanide-based single-ion magnets have attracted much interest due to their great
potential for information storage at the level of one molecule. Among various strategies to …