Atomically precise noble metal nanoclusters as efficient catalysts: a bridge between structure and properties

Y Du, H Sheng, D Astruc, M Zhu - Chemical reviews, 2019 - ACS Publications
Improving the knowledge of the relationship between structure and properties is
fundamental in catalysis. Recently, researchers have developed a variety of well-controlled …

Importance of size and contact structure of gold nanoparticles for the genesis of unique catalytic processes

T Ishida, T Murayama, A Taketoshi, M Haruta - Chemical reviews, 2019 - ACS Publications
Since the discovery of catalysis by Au nanoparticles (NPs), unique catalytic features of Au
have appeared that are greatly different from those of Pd and Pt. In this Review, we aimed to …

Supported metal clusters: fabrication and application in heterogeneous catalysis

C Dong, Y Li, D Cheng, M Zhang, J Liu, YG Wang… - ACS …, 2020 - ACS Publications
Different from isolated metal atoms and large metal nanoparticles (NPs), supported metal
clusters (SMCs) possess distinct geometric and electronic structures and thus exhibit …

[HTML][HTML] Synthetic strategies of supported atomic clusters for heterogeneous catalysis

H Rong, S Ji, J Zhang, D Wang, Y Li - Nature Communications, 2020 - nature.com
Supported atomic clusters with uniform metal sites and definite low-nuclearity are
intermediate states between single-atom catalysts (SACs) and nanoparticles in size …

Metal catalysts for heterogeneous catalysis: from single atoms to nanoclusters and nanoparticles

L Liu, A Corma - Chemical reviews, 2018 - ACS Publications
Metal species with different size (single atoms, nanoclusters, and nanoparticles) show
different catalytic behavior for various heterogeneous catalytic reactions. It has been shown …

[HTML][HTML] Atomic/molecular layer deposition for energy storage and conversion

Y Zhao, L Zhang, J Liu, K Adair, F Zhao… - Chemical Society …, 2021 - pubs.rsc.org
Energy storage and conversion systems, including batteries, supercapacitors, fuel cells,
solar cells, and photoelectrochemical water splitting, have played vital roles in the reduction …

Small angle X-ray scattering for nanoparticle research

T Li, AJ Senesi, B Lee - Chemical reviews, 2016 - ACS Publications
X-ray scattering is a structural characterization tool that has impacted diverse fields of study.
It is unique in its ability to examine materials in real time and under realistic sample …

[HTML][HTML] Simple size-controlled synthesis of Au nanoparticles and their size-dependent catalytic activity

P Suchomel, L Kvitek, R Prucek, A Panacek, A Halder… - Scientific reports, 2018 - nature.com
The controlled preparation of Au nanoparticles (NPs) in the size range of 6 to 22 nm is
explored in this study. The Au NPs were prepared by the reduction of tetrachloroauric acid …

Catalysis by clusters with precise numbers of atoms

EC Tyo, S Vajda - Nature nanotechnology, 2015 - nature.com
Clusters that contain only a small number of atoms can exhibit unique and often unexpected
properties. The clusters are of particular interest in catalysis because they can act as …

[HTML][HTML] Size sensitivity of supported Ru catalysts for ammonia synthesis: From nanoparticles to subnanometric clusters and atomic clusters

L Li, YF Jiang, T Zhang, H Cai, Y Zhou, B Lin, X Lin… - Chem, 2022 - cell.com
Ammonia synthesis is structure sensitive, and a minute change in the catalyst structure
would cause a dramatic change in activity. To date, none of the studies reveal the metal size …