Functional metal–organic frameworks for catalytic applications

C Xu, R Fang, R Luque, L Chen, Y Li - Coordination chemistry reviews, 2019 - Elsevier
Abstract Metal–organic frameworks (MOFs), have received great attention for catalytic
applications, which are regarded to combine the advantages of homogeneous and …

Supramolecular catalysis. Part 2: artificial enzyme mimics

M Raynal, P Ballester, A Vidal-Ferran… - Chemical Society …, 2014 - pubs.rsc.org
The design of artificial catalysts able to compete with the catalytic proficiency of enzymes is
an intense subject of research. Non-covalent interactions are thought to be involved in …

Advanced crystallisation methods for small organic molecules

JP Metherall, RC Carroll, SJ Coles, MJ Hall… - Chemical Society …, 2023 - pubs.rsc.org
Molecular materials based on small organic molecules often require advanced structural
analysis, beyond the capability of spectroscopic techniques, to fully characterise them. In …

Functional behaviour from controlled self-assembly: challenges and prospects

MD Ward, PR Raithby - Chemical society reviews, 2013 - pubs.rsc.org
Many naturally occurring systems show us how multi-component supramolecular
assemblies can generate useful functional behaviour. In this article the problems and …

Crystalline Sponge Method: X‐ray Structure Analysis of Small Molecules by Post‐Orientation within Porous Crystals—Principle and Proof‐of‐Concept Studies

N Zigon, V Duplan, N Wada… - Angewandte Chemie …, 2021 - Wiley Online Library
This Review discusses, along with the historical background, the principles as well as proof‐
of‐concept studies of the crystalline sponge (CS) method, a new single‐crystal X‐ray …

Stereoselective Solid‐State Synthesis of Substituted Cyclobutanes Assisted by Pseudorotaxane‐like MOFs

FL Hu, Y Mi, C Zhu, BF Abrahams… - Angewandte …, 2018 - Wiley Online Library
Regioselective photodimerization of trans‐4‐styrylpyridine (4‐spy) derivatives is performed
using pseudorotaxane‐like Zn‐based metal organic frameworks MOFs as templates. The …

Design and self-assembly of hexahedral coordination cages for cascade reactions

J Jiao, Z Li, Z Qiao, X Li, Y Liu, J Dong, J Jiang… - Nature …, 2018 - nature.com
The search for supramolecular reactors that contain no catalytically active sites but can
promote chemical transformations has received significant attention, but it remains a …

Diastereoselective guest-shape dependent [2+ 2]-photodimerization of 2-cyclopenten-1-one trapped within a metal–organic framework

PA Demakov, DN Dybtsev, VP Fedin - Chemical Communications, 2023 - pubs.rsc.org
UV-induced [2+ 2] dimerization of 2-cyclopenten-1-one and 2-methyl-2-cyclopenten-1-one
was successfully carried out in a single-crystal-to-single-crystal manner within a porous …

Selective photodimerization in a cyclodextrin metal–organic framework

XY Chen, H Chen, L Đorđević, QH Guo… - Journal of the …, 2021 - ACS Publications
For the most part, enzymes contain one active site wherein they catalyze in a serial manner
chemical reactions between substrates both efficiently and rapidly. Imagine if a situation …

Metal-organic materials with triazine-based ligands: From structures to properties and applications

MH Yu, XT Liu, B Space, Z Chang, XH Bu - Coordination Chemistry …, 2021 - Elsevier
Triazine-based ligands, featuring C 3-symmetry configuration, electron-deficient and other
triazine moiety determined characteristics, have facilitated the construction of a diverse set of …