Abstract gem‐Difluorocyclopropanes (F2CPs) have aroused considerable attention not only
from the structural perspective but also due to their ability to participate in various valuable …

An unprecedented Pd‐catalyzed fluorinative bifunctionalization of aziridines and azetidines
was successfully developed via regioselective C− C and C− F bond cleavage of gem …

As a special class of cyclopropanes, gem-difluorinated cyclopropanes have many
fascinating properties as a result of the gem-difluoro substitution; thus, their reactions have …

Developing new strategies to enable chemo-and regioselective reductions is an important
topic in chemical research. Herein, an efficient and regioselective Pd/IPrBIDEA-catalyzed …

The unique properties of the fluorine-containing compounds and their widespread
applications raise the demand for dependable synthetic methods on the precise introduction …

Defluorinative manipulation of polyfluorinated molecules has shown great promise due to its
granting of synthetic versatility to inert C− F bonds. The development of chemo‐, stereo‐and …

Controlling the selectivity of synthetically useful reactions has been a longstanding objective
of organic chemistry. We report a regiodivergent synthetic protocol allowing access to …

Palladium-catalyzed synthesis of 3-acyl and-allyl indoles has been realized by merging
nucleophilic cyclization of ortho-alkynylanilines with ring opening of three-membered rings …

The control of linear/branched selectivity is one of the major focuses in transition-metal
catalyzed allyl–allyl cross-coupling reactions, in which bond connection occurs at the …

A new Co-catalyzed sequential C–C and C–F activation of gem-difluorinated cyclopropanes
(gem-FCPs) to form nucleophilic fluoroallylcobalt, followed by addition to aldehydes, is …