Syntheses and applications of disubstituted [2.2] paracyclophanes

ORP David - Tetrahedron, 2012 - Elsevier
[2.2] Paracyclophane 1 (Pc) was prepared and isolated by Brown and Farthing in 1949.
Cram was the first to systematically investigate its chemical behaviour, helping to grasp the …

Vibronic contributions to charge transport across molecular junctions

JG Kushmerick, J Lazorcik, CH Patterson… - Nano Letters, 2004 - ACS Publications
We report low-temperature charge transport measurements of metal− molecule− metal
junctions. Studies on insulating alkyl and π-conjugated molecular wires provide …

Chemically patterned microspheres for controlled nanoparticle assembly in the construction of SERS hot spots

G Braun, I Pavel, AR Morrill, DS Seferos… - Journal of the …, 2007 - ACS Publications
An important challenge in developing ultra-sensitive surface enhanced Raman
spectroscopy (SERS) platforms lies in the creation of nanoscale hot spots, locations where …

Color-tuned highly fluorescent organic nanowires/nanofabrics: easy massive fabrication and molecular structural origin

BK An, SH Gihm, JW Chung, CR Park… - Journal of the …, 2009 - ACS Publications
The development of one-dimensional fluorescent nanowires (1D-NWs) and their higher-
dimensional architectures such as nanowebs and nanofabrics (2D-NFs) could open a new …

Novel organic materials through control of multichromophore interactions

GC Bazan - The Journal of organic chemistry, 2007 - ACS Publications
The function of organic semiconducting and light-harvesting materials depends on the
organization of the individual molecular components. Our group has tackled the problem of …

Optically active cyclic compounds based on planar chiral [2.2] paracyclophane: extension of the conjugated systems and chiroptical properties

M Gon, Y Morisaki, Y Chujo - Journal of Materials Chemistry C, 2015 - pubs.rsc.org
A series of optically active cyclic compounds based on the planar chiral tetrasubstituted [2.2]
paracyclophane core were synthesized to obtain luminescent materials with excellent …

Formation of high-quality self-assembled monolayers of conjugated dithiols on gold: base matters

H Valkenier, EH Huisman, PA van Hal… - Journal of the …, 2011 - ACS Publications
This Article reports a systematic study on the formation of self-assembled monolayers
(SAMs) of conjugated molecules for molecular electronic (ME) devices. We monitored the …

Self-Assembly and Luminescence of Oligo(p-phenylene vinylene) Amphiphiles

JF Hulvat, M Sofos, K Tajima… - Journal of the American …, 2005 - ACS Publications
We have synthesized a series of amphiphilic molecules consisting of oligo (phenylene
vinylene)(OPV) asymmetrically end-substituted with a hydrophilic poly (ethylene …

Strong Two‐Photon Excited Fluorescence and Stimulated Emission from an Organic Single Crystal of an Oligo (Phenylene Vinylene)

F Gao, Q Liao, ZZ Xu, YH Yue, Q Wang… - Angewandte Chemie …, 2010 - infona.pl
Low in, high out: Single crystals of a thiomethyl‐terminated oligo (phenylene vinylene)
exhibit unique photonic properties including strong anisotropic solid‐state fluorescence (see …

Synthesis of Optically Active, X‐Shaped, Conjugated Compounds and Dendrimers Based on Planar Chiral [2.2] Paracyclophane, Leading to Highly Emissive …

M Gon, Y Morisaki, R Sawada… - Chemistry–A European …, 2016 - Wiley Online Library
Optically active, Fréchet‐type dendrimers containing an emissive X‐shaped π‐electron
system as the core unit were synthesized. Gram‐scale optical resolution and transformations …