CO 2-fixation into cyclic and polymeric carbonates: principles and applications

AJ Kamphuis, F Picchioni, PP Pescarmona - Green chemistry, 2019 - pubs.rsc.org
The reaction between carbon dioxide and epoxides is an attractive pathway for CO2-
utilisation as it can lead to the formation of two different, yet valuable, products: cyclic and …

Recyclable/degradable materials via the insertion of labile/cleavable bonds using a comonomer approach

C Lefay, Y Guillaneuf - Progress in Polymer Science, 2023 - Elsevier
Polymers have many advantages such as low weight, low cost, and, importantly, stability
under thermal, chemical, and mechanical stress. This stability, on the other hand, leads to …

Carbon dioxide-based functional polycarbonates: Metal catalyzed copolymerization of CO2 and epoxides

Y Wang, DJ Darensbourg - Coordination Chemistry Reviews, 2018 - Elsevier
Proof of principles studies by Inoue and coworkers in the late 1960s clearly illustrated the
poorly controlled coupling of CO 2 and epoxides to provide polycarbonates. These early …

Copolymerization of carbon dioxide and epoxides by metal coordination complexes

CM Kozak, K Ambrose, TS Anderson - Coordination Chemistry Reviews, 2018 - Elsevier
The catalytic copolymerization of CO 2 with epoxides to give polycarbonates was discovered
nearly 50 years ago. The last 10 years have been particularly exciting for the development …

Functional polycarbonates from carbon dioxide and tailored epoxide monomers: degradable materials and their application potential

M Scharfenberg, J Hilf, H Frey - Advanced Functional Materials, 2018 - Wiley Online Library
Aliphatic polycarbonates synthesized from carbon dioxide (CO2) and epoxides are resource‐
saving, highly biocompatible and biodegradable polymers. Since the discovery of the …

Glycerol Oxidation Pairs with Carbon Monoxide Reduction for Low-Voltage Generation of C2 and C3 Product Streams

H Yadegari, A Ozden, T Alkayyali, V Soni… - ACS Energy …, 2021 - ACS Publications
Electrochemical carbon dioxide reduction to multicarbon products provides the storage of
renewable energy in the form of chemical bonds, as well as a means to displace fossil …

Chemical synthesis of polysaccharides and polysaccharide mimetics

R Xiao, MW Grinstaff - Progress in Polymer Science, 2017 - Elsevier
Polysaccharides are ubiquitous in nature, and play many critical roles in biology. As such,
the synthesis of polysaccharides and of polymers mimicking the structure or function of …

Microplastics and biobased polymers to combat plastics waste

K Kumar, R Umapathi, SM Ghoreishian, JN Tiwari… - Chemosphere, 2023 - Elsevier
Microplastics (MPs) have become the major global concern due to their adverse effects on
the environment, human health, and hygiene. These complex molecules have numerous …

Sustainable polycarbonate adhesives for dry and aqueous conditions with thermoresponsive properties

A Beharaj, EZ McCaslin, WA Blessing… - Nature …, 2019 - nature.com
Pressure sensitive adhesives are ubiquitous in commodity products such as tapes,
bandages, labels, packaging, and insulation. With single use plastics comprising almost half …

Direct Copolymerization of CO2 and Diols

M Tamura, K Ito, M Honda, Y Nakagawa, H Sugimoto… - Scientific reports, 2016 - nature.com
Direct polymerization of CO2 and diols is promising as a simple and environmental-benign
method in place of conventional processes using high-cost and/or hazardous reagents such …