Novel synthetic methods published since 2005 affording carbohydrates containing sulfur
atom (s) are reviewed. The review is divided to subchapters based on the position of sulfur …

Controlling the chemical glycosylation reaction remains the major challenge in the synthesis
of oligosaccharides. Though 1, 2-trans glycosidic linkages can be installed using …

The broad application of well-defined synthetic oligosaccharides in glycobiology and
glycobiotechnology is largely hampered by the lack of sufficient amounts of synthetic …

An effective regiodivergent synthesis toward 1-and 3-thiosugars was achieved through
palladium and cobalt catalysis, respectively. β-1-Thiosugars were obtained from 3, 4-O …

Acetal substitution reactions of α‐halogenated five‐and six‐membered rings can be highly
stereoselective. Erosion of stereoselectivity occurs as nucleophilicity increases, which is …

Immunoglobulins are biomolecules involved in defence against foreign substances.
Flexibility is key to their functional properties in relation to antigen binding and receptor …

Analogues of the canonical nucleosides required for nucleic acid synthesis have a
longstanding presence and proven capability within antiviral and anticancer research. 4 …

Uronic acids are carbohydrates carrying a terminal carboxylic acid and have a unique
reactivity in stereoselective glycosylation reactions. Herein, the competing intramolecular …

The 3D shape of glycosyl oxocarbenium ions determines their stability and reactivity and the
stereochemical course of SN1 reactions taking place on these reactive intermediates is …

Adenosine diphosphate (ADP) ribosylation is an important post-translational modification
(PTM) that plays a role in a wide variety of cellular processes. To study the enzymes …