Organic reactions in aqueous media catalyzed by nickel
The expansion of catalytic methods is a focus of contemporary interest due to the adverse
effects of the manufacturing process of fine chemicals, pharmaceuticals, and materials on …
effects of the manufacturing process of fine chemicals, pharmaceuticals, and materials on …
Beyond the traditional roles of Ag in catalysis: the transmetalating ability of organosilver (I) species in Pd-catalysed reactions
ÁL Mudarra, SM de Salinas… - Organic & Biomolecular …, 2019 - pubs.rsc.org
Silver salts are one of the most widely used additives in Pd-catalysed transformations. Apart
from acting as a halide scavenger and/or an external oxidant, over the past decade it has …
from acting as a halide scavenger and/or an external oxidant, over the past decade it has …
nBu4N+[AgI(CF3)2]−: Trifluoromethylated Argentate Derived from Fluoroform and Its Reaction with (Hetero)Aryl Diazonium Salts
Z Lu, L Wang, M Hughes, S Smith, Q Shen - Organic Letters, 2023 - ACS Publications
The preparation of a well-defined trifluoromethylated argentate n Bu4N+ [Ag (CF3) 2]− 1
from fluoroform was described. The complex was stable in the solid state and in solution …
from fluoroform was described. The complex was stable in the solid state and in solution …
Argentination of Fluoroform: Preparation of a Stable AgCF3 Solution with Diverse Reactivities
JX Xiang, Y Ouyang, XH Xu… - Angewandte Chemie …, 2019 - Wiley Online Library
The transformation of a large‐volume industrial by‐product and stable greenhouse gas
fluoroform (HCF3) to useful products has recently received significant attention. Now, a …
fluoroform (HCF3) to useful products has recently received significant attention. Now, a …
Bi-and trinuclear coinage metal complexes of a PNNP ligand featuring metallophilic interactions and an unusual charge separation
M Dahlen, M Kehry, S Lebedkin, MM Kappes… - Dalton …, 2021 - pubs.rsc.org
A selective synthesis of bi-and trinuclear complexes featuring a tetradentate monoanionic
PNNP ligand is presented. The binuclear coinage metal complexes show a typical fourfold …
PNNP ligand is presented. The binuclear coinage metal complexes show a typical fourfold …
Aryl–CF3 Coupling from Phosphinoferrocene-Ligated Palladium(II) Complexes
DM Ferguson, JR Bour, AJ Canty, JW Kampf… - …, 2019 - ACS Publications
This article describes a detailed investigation of ligand effects on Ph–CF3 coupling from
phosphinoferrocene-ligated PdII (Ph)(CF3) complexes. This study reveals that increasing …
phosphinoferrocene-ligated PdII (Ph)(CF3) complexes. This study reveals that increasing …
Cross‐Coupling through Ag (I)/Ag (III) Redox Manifold
L Demonti, N Saffon‐Merceron… - … A European Journal, 2021 - Wiley Online Library
In ample variety of transformations, the presence of silver as an additive or co‐catalyst is
believed to be innocuous for the efficiency of the operating metal catalyst. Even though Ag …
believed to be innocuous for the efficiency of the operating metal catalyst. Even though Ag …
Redefining the Mechanistic Scenario of Carbon−Sulfur Nucleophilic Coupling via High‐Valent Cp*CoIV Species
S López‐Resano, S Martínez de Salinas… - Angewandte Chemie …, 2021 - Wiley Online Library
The potential access to CoIV species for promoting transformations that are particularly
challenging at CoIII still remains underexploited in the context of Cp* Co‐catalyzed C− H …
challenging at CoIII still remains underexploited in the context of Cp* Co‐catalyzed C− H …
C(sp2)-CF3 Reductive Elimination from Well-Defined Argentate(III) Complexes [nBu4N][Ag(Ar)(CF3)3]
The preparation of a series of well-defined, shelf-stable square planar aryl (tris
(trifluoromethyl)) argentate (III) complexes [n Bu4N]+[Ag (Ar)(CF3) 3]− and their C (sp2)-CF3 …
(trifluoromethyl)) argentate (III) complexes [n Bu4N]+[Ag (Ar)(CF3) 3]− and their C (sp2)-CF3 …
Safe Entry to Ag(I)/Ag(III) Mixed Valence Salts Containing the Homoleptic Ag(III) Anion [Ag(CF3)4]−
L Demonti, H Tabikh… - European Journal of …, 2023 - Wiley Online Library
The synthesis of Naumann's AgI/AgIII mixed valence salt [AgI]+[AgIII (CF3) 4]−(Ag‐1) is
revisited. Ag‐1 is now safely available in half gram scale upon 2e− oxidation of AgF in …
revisited. Ag‐1 is now safely available in half gram scale upon 2e− oxidation of AgF in …