Catalytic Asymmetric Oxygenations with the Environmentally Benign Oxidants H2O2 and O2

KP Bryliakov - Chemical reviews, 2017 - ACS Publications
The discovery of simple and efficient catalyst systems for the asymmetric
oxofunctionalization of hydrocarbons is a challenging task of catalytic chemistry. In this …

Modern stereoselective synthesis of chiral sulfinyl compounds

E Wojaczyńska, J Wojaczyński - Chemical reviews, 2020 - ACS Publications
Chiral sulfinyl compounds, sulfoxides, sulfoximines, sulfinamides, and other derivatives, play
an important role in asymmetric synthesis as versatile auxiliaries, ligands, and catalysts …

Organocatalysis in aqueous media

MP van Der Helm, B Klemm, R Eelkema - Nature Reviews Chemistry, 2019 - nature.com
Even though enzymes are the cornerstones of living systems, it has so far proven difficult to
deploy artificial catalysts in a biological setting. Organocatalysts are arguably well-suited …

Chiral sulfoxides: advances in asymmetric synthesis and problems with the accurate determination of the stereochemical outcome

J Han, VA Soloshonok, KD Klika, J Drabowicz… - Chemical Society …, 2018 - pubs.rsc.org
Chiral sulfoxides are in extremely high demand in nearly every sector of the chemical
industry concerned with the design and development of new synthetic reagents, drugs, and …

Biomimetic asymmetric catalysis

X Xiao, K Xu, ZH Gao, ZH Zhu, C Ye, B Zhao… - Science China …, 2023 - Springer
Enzymes are the core for biological transformations in nature. Their structures and functions
have drawn enormous attention from biologists as well as chemists since last century. The …

Biomimetic flavin-catalysed reactions for organic synthesis

H Iida, Y Imada, SI Murahashi - Organic & biomolecular chemistry, 2015 - pubs.rsc.org
Using simple riboflavin related compounds as biomimetic catalysts, catalytic oxidation of
various substrates with hydrogen peroxide or molecular oxygen can be performed …

Artificial flavin systems for chemoselective and stereoselective oxidations

R Cibulka - European Journal of Organic Chemistry, 2015 - Wiley Online Library
Flavinium salts, both isoalloxazinium and alloxazinium derivatives, are useful
organocatalysts of redox reactions, and particularly in recent years, the number of …

[HTML][HTML] Molecular Editing of Flavins for Catalysis

A Rehpenn, A Walter, G Storch - Synthesis, 2021 - thieme-connect.com
The diverse activity of flavoenzymes in organic transformations has fascinated researchers
for a long time. However, when applied outside an enzyme environment, the isolated flavin …

Flavin-catalyzed aerobic oxidation of sulfides and thiols with formic acid/triethylamine

SI Murahashi, D Zhang, H Iida, T Miyawaki… - Chemical …, 2014 - pubs.rsc.org
Flavin-catalyzed aerobic oxidation of sulfides and thiols with formic acid/triethylamine -
Chemical Communications (RSC Publishing) DOI:10.1039/C4CC05216A Royal Society of …

Biomimetic aerobic oxidative hydroxylation of arylboronic acids to phenols catalysed by a flavin derivative

H Kotoučová, I Strnadová, M Kovandová… - Organic & …, 2014 - pubs.rsc.org
Flavin-catalysed oxidative hydroxylation of substituted arylboronic acids by molecular
oxygen with the assistance of hydrazine or ascorbic acid resulted in phenols in high yields …