Among the wide variety of organometallic compounds, the relatively cheap and safely
handled nontransition-metal derivatives, in particular organolithium, organomagnesium …

Transformations using organometallic complexes have played a central role in modern
organic synthesis. The types of reactions based on organometallic complexes can be …

The present review deals with the chemistry of the organotitanium species formed by the
reaction of titanium alkoxides of the form XTi (OR) 3 (X¼Me, Cl, OR; R¼alkyl) and excess …

In this report, we describe a halo-Prins/aryl halo-Nazarov cyclization strategy that employs
readily available starting materials, inexpensive reagents, and convenient reaction …

Treatment of the titanacyclopentadiene compound [Ti (OC6H3Ph2-2, 6) 2 (C4Et4)](3)(
OC6H3Ph2-2, 6= 2, 6-diphenylphenoxide) with olefins leads to the formation of a variety of …

This account describes synthetic transformations of unsaturated hydrocarbons, such as
alkynes, alkenes, and dienes, mediated by the divalent titanium reagent Ti (O‐i‐Pr) 4/2 i …

Cyclopropanes are characterized by high ring‐strain energy and have been employed as
useful building blocks in organic synthesis. The incorporation of a heteroatom donor …

New Mo (II) complexes BnEt3N+ [Mo (CO) 4ClBr2]-(A) and Mo (CO) 5 (OTf) 2 (B) and their W
(II) congeners D and E have been developed as catalysts for the title reactions. Unlike other …

Treatment of a variety of 1, 2-dien-7-ynes with a slight excess of (η2-propene) Ti (Oi-Pr) 2
(1), prepared in situ from Ti (Oi-Pr) 4 and 2 equiv of i-PrMgCl in ether, afforded 1-alkenyl-2 …

Treatment of N-(2-or 3-alkynyl) amino esters with a low-valent titanium reagent diisopropoxy
(η2-propene) titanium (1), generated in situ by the reaction of Ti (Oi-Pr) 4 and 2 i-PrMgCl …