Recent Advances in Alkenyl sp2 C–H and C–F Bond Functionalizations: Scope, Mechanism, and Applications

MZ Lu, J Goh, M Maraswami, Z Jia, JS Tian… - Chemical …, 2022 - ACS Publications
Alkenes and their derivatives are featured widely in a variety of natural products,
pharmaceuticals, and advanced materials. Significant efforts have been made toward the …

Bidentate directing groups: an efficient tool in C–H bond functionalization chemistry for the expedient construction of C–C bonds

S Rej, Y Ano, N Chatani - Chemical reviews, 2020 - ACS Publications
During the past decades, synthetic organic chemistry discovered that directing group
assisted C–H activation is a key tool for the expedient and siteselective construction of C–C …

3d transition metals for C–H activation

P Gandeepan, T Müller, D Zell, G Cera… - Chemical …, 2018 - ACS Publications
C–H activation has surfaced as an increasingly powerful tool for molecular sciences, with
notable applications to material sciences, crop protection, drug discovery, and …

[HTML][HTML] A comprehensive overview of directing groups applied in metal-catalysed C–H functionalisation chemistry

C Sambiagio, D Schönbauer, R Blieck… - Chemical Society …, 2018 - pubs.rsc.org
The present review is devoted to summarizing the recent advances (2015–2017) in the field
of metal-catalysed group-directed C–H functionalisation. In order to clearly showcase the …

Recent advances in chelation-assisted site-and stereoselective alkenyl C–H functionalization

J Zhang, X Lu, C Shen, L Xu, L Ding… - Chemical Society …, 2021 - pubs.rsc.org
Olefinic C–H functionalization represents an atom-and step economic approach to valuable
olefin derivatives from simpler ones, but controlling the selectivity remains a challenge …

Direct functionalization of C− H bonds by iron, nickel, and cobalt catalysis

G Pototschnig, N Maulide… - Chemistry–A European …, 2017 - Wiley Online Library
Non‐precious‐metal‐catalyzed reactions are of increasing importance in chemistry due to
the outstanding ecological and economic properties of these metals. In the subfield of metal …

Chelation-assisted nickel-catalyzed C− H functionalizations

SM Khake, N Chatani - Trends in Chemistry, 2019 - cell.com
Use of a directing group in C–H functionalizations, often referred to as chelation assistance,
is one of the most reliable methods for achieving highly efficient and highly site-selective …

A Guide to Directing Group Removal: 8‐Aminoquinoline

LS Fitzgerald, ML O'Duill - Chemistry–A European Journal, 2021 - Wiley Online Library
The use of directing groups allows high levels of selectivity to be achieved in transition metal‐
catalyzed transformations. Efficient removal of these auxiliaries after successful …

Recent advances and prospects in nickel-catalyzed C–H activation

NA Harry, S Saranya, SM Ujwaldev… - Catalysis Science & …, 2019 - pubs.rsc.org
Nickel-catalyzed C–H activation has become a predominant and ubiquitous research area
in organic chemistry. Direct functionalization of inert C–H bonds to create functionally …

Sterically controlled late-stage C–H alkynylation of arenes

A Mondal, H Chen, L Flämig, P Wedi… - Journal of the …, 2019 - ACS Publications
Phenylacetylenes are key structural motifs in organic chemistry, which find widespread
applications in bioactive molecules, synthetic intermediates, functional materials, and …