The past decades in organic chemistry have witnessed significant improvements in synthetic
efficiency as a result of considerable progress in cascade reactions, tandem reactions, and …

Alkynes are one of the most versatile functional groups as synthetic handles. They allow for
a direct access to partially or fully substituted alkenes through difunctionalization reactions …

Complexity‐increasing Domino reactions comprising C− H allenylation, a Diels–Alder
reaction, and a retro‐Diels–Alder reaction were realized by a versatile catalyst derived from …

Tetraarylethylenes (TAEs) have been gaining attention from various scientific disciplines for
their characteristic chemical and physical properties. From the synthetic perspective …

A new free carbon radical was obtained in a microwave‐assisted solvothermal reaction of
the primary amine (1‐methyl‐1H‐benzo [d] imidazol‐2‐yl) methanamine with FeCl3⋅ 6 H2O …

An intramolecular Pd‐catalyzed formal anti‐carboalkoxylation reaction is presented that
provides access to tetrasubstituted enol ethers. The key to success is a cascade consisting …

An intramolecular Pd‐catalyzed trans‐dicarbofunctionalization of internal alkynes using aryl
bromides and aryl stannanes is presented. Tetrasubstituted double bonds embedded in an …

Alkyne aminopalladation reactions starting from tosylamides are reported. The emerging
vinylic Pd species are converted either in an intramolecular Heck reaction with olefinic units …

An efficient, highly regio‐and stereoselective protocol for the synthesis of tetrasubstituted
olefins was developed to take place by a palladium (0)‐catalyzed triple domino process. It …

A new method for the stereoselective cross‐coupling reaction of arylzinc chlorides with
trisubstituted enol phosphates is described. The developed method requires aluminum …