Photoactive copper complexes: properties and applications

J Beaudelot, S Oger, S Perusko, TA Phan… - Chemical …, 2022 - ACS Publications
Photocatalyzed and photosensitized chemical processes have seen growing interest
recently and have become among the most active areas of chemical research, notably due …

TADF: Enabling luminescent copper (i) coordination compounds for light-emitting electrochemical cells

CE Housecroft, EC Constable - Journal of Materials Chemistry C, 2022 - pubs.rsc.org
The last decade has seen a surge of interest in the emissive behaviour of copper (I)
coordination compounds, both neutral compounds that may have applications in organic …

Two-coordinate thermally activated delayed fluorescence coinage metal complexes: Molecular design, photophysical characters, and device application

TY Li, SJ Zheng, PI Djurovich, ME Thompson - Chemical Reviews, 2024 - ACS Publications
Since the emergence of the first green light emission from a fluorescent thin-film organic light
emitting diode (OLED) in the mid-1980s, a global consumer market for OLED displays has …

The early years of 2, 2′-bipyridine—A ligand in its own lifetime

EC Constable, CE Housecroft - Molecules, 2019 - mdpi.com
The first fifty years of the chemistry of 2, 2′-bipyridine are reviewed from its first discovery in
1888 to the outbreak of the second global conflict in 1939. The coordination chemistry and …

The golden age of thermally activated delayed fluorescence materials: design and exploitation

JM Dos Santos, D Hall, B Basumatary… - Chemical …, 2024 - ACS Publications
Since the seminal report by Adachi and co-workers in 2012, there has been a veritable
explosion of interest in the design of thermally activated delayed fluorescence (TADF) …

Recent Advances in Solid‐State Lighting Devices Using Transition Metal Complexes Exhibiting Thermally Activated Delayed Fluorescent Emission Mechanism

GU Mahoro, J Fernandez‐Cestau… - Advanced Optical …, 2020 - Wiley Online Library
This review focuses on the state‐of‐the‐art of solid‐state lighting devices (SSLDs)—that is,
organic light‐emitting diodes (OLEDs) and light‐emitting electrochemical cells (LECs) …

Wide-bite-angle diphosphine ligands in thermally activated delayed fluorescent copper (I) complexes: impact on the performance of electroluminescence applications

C Li, CFR Mackenzie, SA Said, AK Pal… - Inorganic …, 2021 - ACS Publications
We report a series of seven cationic heteroleptic copper (I) complexes of the form [Cu (P^
P)(dmphen)] BF4, where dmphen is 2, 9-dimethyl-1, 10-phenanthroline and P^ P is a …

The surprising effects of sulfur: achieving long excited-state lifetimes in heteroleptic copper (I) emitters

I Nohara, C Wegeberg, M Devereux… - Journal of Materials …, 2022 - pubs.rsc.org
A series of heteroleptic [Cu (N^ N)(P^ P)][PF6] complexes is reported in which N^ N is a di
(methylsulfanyl)-1, 10-phenanthroline (2, 9-, 3, 8-or 4, 7-(MeS) 2phen) or di (methoxy)-1, 10 …

Cu Photoredox Catalysts Supported by a 4, 6-Disubstituted 2, 2′-Bipyridine Ligand: Application in Chlorotrifluoromethylation of Alkenes

M Alkan-Zambada, X Hu - Organometallics, 2018 - ACS Publications
Interest in base metal catalysis motivates the development of Cu-based photoredox catalysts
for organic synthesis. However, only a few Cu catalysts have been applied in photoredox …

Novel Red‐Emitting Copper (I) Complexes with Pyrazine and Pyrimidinyl Ancillary Ligands for White Light‐Emitting Electrochemical Cells

E Fresta, GU Mahoro, LM Cavinato… - Advanced Optical …, 2022 - Wiley Online Library
The synthesis, photophysical/electrochemical characterization, and implementation in light‐
emitting electrochemical cells (LECs) of three novel red‐emitting heteroleptic [Cu (N^ N)(P …