The amide bond is one of the most important functional groups in chemistry and biology. 1
Due to the strong resonance interaction between nN and π* C O orbitals (Figure 1), 2 the …

Phenylglycinol‐derived oxazolopiperidone lactams are exceptionally versatile building
blocks for the enantioselective construction of structurally diverse piperidine‐containing …

The present review highlights the synthetic procedures reported for the preparation of
oxazolo [3, 2-a] pyridines as a class of 5-6 bicyclic heterocycles with a nitrogen atom at the …

The stereochemical outcome of the enolate dialkylation of simple phenylglycinol-derived
oxazolopiperidone lactams is studied. High stereoselectivities in the generation of the …

Explorations into a series of different approaches for 9‐membered carbocycle formation
have afforded the first reported example of a 9‐exo‐dig ring closure via a AuIII‐promoted …

An enantioselective two-step route to substituted benzo [a]-and indolo [2, 3-a] quinolizidines
has been developed. It consists of (i) a stereoselective cyclocondensation of a racemic or …

Frogs of the neotropical family Dendrobatidae produce a remarkably diverse array of
biologically active alkaloids. One of the major classes of these amphibian alkaloids [1] are …

A Direct Stereoselective Approach to trans-2,3-Disubstituted Piperidines: Application in the
Synthesis of 2-Epi-CP-99,994 and (+)-Epilupinine | Organic Letters ACS ACS Publications …

A straightforward procedure for the synthesis of enantiopure polysubstituted piperidines is
reported. It involves the direct generation of chiral non‐racemic oxazolo [3, 2‐a] piperidone …

The enantioselective construction of the 3-ethylindolo [2, 3-a] quinolizidine moiety present in
numerous indole alkaloids is reported, the key steps being a stereoselective …