Atom tunneling in chemistry
Quantum mechanical tunneling of atoms is increasingly found to play an important role in
many chemical transformations. Experimentally, atom tunneling can be indirectly detected …
many chemical transformations. Experimentally, atom tunneling can be indirectly detected …
High-pressure oxidation of methane
H Hashemi, JM Christensen, S Gersen, H Levinsky… - Combustion and …, 2016 - Elsevier
Methane oxidation at high pressures and intermediate temperatures was investigated in a
laminar flow reactor and in a rapid compression machine (RCM). The flow-reactor …
laminar flow reactor and in a rapid compression machine (RCM). The flow-reactor …
Uncertainty quantification of a newly optimized methanol and formaldehyde combustion mechanism
A detailed reaction mechanism for methanol combustion that is capable of describing
ignition, flame propagation and species concentration profiles with high accuracy has been …
ignition, flame propagation and species concentration profiles with high accuracy has been …
A detailed combined experimental and theoretical study on dimethyl ether/propane blended oxidation
In this paper, a binary fuel model for dimethyl ether (DME) and propane is developed, with a
focus on engine-relevant conditions (10–50 atm and 550–2000 K). New rapid compression …
focus on engine-relevant conditions (10–50 atm and 550–2000 K). New rapid compression …
Plug-flow reactor and shock-tube study of the oxidation of very fuel-rich natural gas/DME/O2 mixtures
D Kaczmarek, J Herzler, S Porras, S Shaqiri… - Combustion and …, 2021 - Elsevier
A polygeneration process with the ability to provide work, heat, and useful chemicals
according to the specific demand is a promising alternative to traditional energy conversion …
according to the specific demand is a promising alternative to traditional energy conversion …
Numerical and experimental investigations on the particle formation in oxymethylene ethers (OMEn, n= 2− 4)/ethylene premixed flames
Alternative synthetic fuels can be produced by renewable energy sources and represent a
potential route for solving long-term energy storage. Among them, oxygenated fuels have …
potential route for solving long-term energy storage. Among them, oxygenated fuels have …
Microorganisms as New Sources of Energy
The use of fossil energy sources has a negative impact on the economic and socio-political
stability of specific regions and countries, causing environmental changes due to the …
stability of specific regions and countries, causing environmental changes due to the …
Shock tube study of ethanol pyrolysis II: Rate constant measurements and modeling
The rate constants of two unimolecular decomposition channels of ethanol, C 2 H 5 OH (+
Ar)= CH 3+ CH 2 OH (+ Ar), and C 2 H 5 OH (+ Ar)= C 2 H 4+ H 2 O (+ Ar) were measured …
Ar)= CH 3+ CH 2 OH (+ Ar), and C 2 H 5 OH (+ Ar)= C 2 H 4+ H 2 O (+ Ar) were measured …
Complete reactants-to-products observation of a gas-phase chemical reaction with broad, fast mid-infrared frequency combs
Molecular diagnostics are a primary tool of modern chemistry, enabling researchers to map
chemical reaction pathways and rates to better design and control chemical systems. Many …
chemical reaction pathways and rates to better design and control chemical systems. Many …
Quantitative measurements of broad-band mid-infrared absorption spectra of formaldehyde, acetaldehyde, and acetone at combustion-relevant temperatures near 5.7 …
Temperature-dependent absorption cross sections of formaldehyde, acetaldehyde, and
acetone are presented for their C double bond O stretching bands near 5.7 µm. The …
acetone are presented for their C double bond O stretching bands near 5.7 µm. The …