Transition‐metal‐catalyzed carboxylation reactions with carbon dioxide

A Tortajada, F Juliá‐Hernández… - Angewandte Chemie …, 2018 - Wiley Online Library
Driven by the inherent synthetic potential of CO2 as an abundant, inexpensive and
renewable C1 chemical feedstock, the recent years have witnessed renewed interest in …

Reactivity of gold complexes towards elementary organometallic reactions

M Joost, A Amgoune… - Angewandte Chemie …, 2015 - Wiley Online Library
For a while, the reactivity of gold complexes was largely dominated by their Lewis acid
behavior. In contrast to the other transition metals, the elementary steps of organometallic …

Oxidant-free oxidative gold catalysis: the new paradigm in cross-coupling reactions

MO Akram, S Banerjee, SS Saswade, V Bedi… - Chemical …, 2018 - pubs.rsc.org
The construction of C–C and C–X (X= hetero atom) bonds is the core aspect for the
assembly of molecules. In this regard, late transition-metal-catalyzed cross-coupling …

N-Heterocyclic carbene (NHC)–copper-catalysed transformations of carbon dioxide

L Zhang, Z Hou - Chemical Science, 2013 - pubs.rsc.org
This minireview gives an overview of the chemical transformations of carbon dioxide (CO2)
catalysed by N-heterocyclic carbene (NHC)–copper complexes. NHC–copper complexes …

C−H Carboxylation of Aromatic Compounds through CO2 Fixation

J Luo, I Larrosa - ChemSusChem, 2017 - Wiley Online Library
Carbon dioxide (CO2) represents the most abundant and accessible carbon source on
Earth. Thus the ability to transform CO2 into valuable commodity chemicals through the …

Facile oxidative addition of aryl iodides to gold (I) by ligand design: bending turns on reactivity

M Joost, A Zeineddine, L Estevez… - Journal of the …, 2014 - ACS Publications
Thanks to rational ligand design, the first gold (I) complexes to undergo oxidative addition of
aryl iodides were discovered. The reaction proceeds under mild conditions and is general …

C− H bond carboxylation with carbon dioxide

J Hong, M Li, J Zhang, B Sun, F Mo - ChemSusChem, 2019 - Wiley Online Library
Carbon dioxide is a nontoxic, renewable, and abundant C1 source, whereas C− H bond
functionalization represents one of the most important approaches to the construction of …

Ligand-Enabled Gold-Catalyzed C(sp2)–N Cross-Coupling Reactions of Aryl Iodides with Amines

MO Akram, A Das, I Chakrabarty, NT Patil - Organic letters, 2019 - ACS Publications
The first example of ancillary (P, N)-ligand-enabled gold-catalyzed C–N cross-coupling
reactions of aryl iodides with amines is reported. The high generality of the reaction in de …

Transition metal complex catalyzed carboxylation reactions with CO2

D Yu, SP Teong, Y Zhang - Coordination Chemistry Reviews, 2015 - Elsevier
Transition metal complexes play a key role in catalytic carboxylation reactions with CO 2.
Various metal complex catalytic systems have been developed for the carboxylation of …

Recent Advances in Carbon Dioxide Capture, Fixation, and Activation by using N‐Heterocyclic Carbenes

L Yang, H Wang - ChemSusChem, 2014 - Wiley Online Library
In the last two decades, CO2 emission has caused a lot of environmental problems. To
mitigate the concentration of CO2 in the atmosphere, various strategies have been …