Quantifying variation in cooperative B–H bond activations using Os (ii) and Os (iii) κ 2-N, S-chelated complexes: same, but different

S Gayen, F Assanar, S Shyamal, DP Dorairaj… - Chemical …, 2024 - pubs.rsc.org
In an effort to investigate small molecule activation by heavier transition metal (TM) based κ2-
N, S-chelated species, we have synthesised a series of bis-κ2-1, 3-N, S-chelated complexes …

The Insertion Reactions of GeCl2 with Mono‐and Bis‐κ2‐N, S‐Chelated Ru (II) Complexes

A Ahmad, F Assanar, U Gupta, P Shukla… - European Journal of … - Wiley Online Library
The dual‐site insertion of GeCl2 into bis‐1, 3‐N, S‐chelated ruthenium complexes,[(PPh3)
2Ru {κ2‐N, S‐(L) 2}],(cis‐1L1 and cis‐1L2; L= NC5H4S (L1); L= NC7H4S2 (L2)) has been …