In the first-row of d-block metals, ten elements are included, such as scandium (Sc, 3d1),
titanium (Ti, 3d2), vanadium (V, 3d3), chromium (Cr, 3d54s1), manganese (Mn, 3d5), iron …

Nitro compounds are an important class of organic molecules with broad application in
organic synthesis, medicinal chemistry, and materials science. Among the variety of …

An organocatalytic and environmentally friendly approach for the selective oxidation of
substituted anilines was developed. Utilizing a 2, 2, 2-trifluoroacetophenone-mediated …

The generation and stabilization of reactive oxygen species (ROS), including the superoxide
radical anion (O 2 radical dot−), have a huge potential in environmental remediation and …

A two-dimensional microporous dinuclear copper (II) trans-1, 4-cyclohexanedicarboxylate,[
CuII, II2 (OOCC6H10COO) 2]⋅ H2O (1), can act as a heterogeneous catalyst for selective …

The interaction of hydrogen peroxide with a range of polycrystalline titanium oxide systems,
including TiO2, TS-1,[Ti]-APO-5 and ion-exchanged Ti-ZSM-5, has been investigated using …

The oxidative transformation of primary amines to their corresponding oximes proceeds with
high efficiency under molecular oxygen diluted with molecular nitrogen (O2/N2= 7/93 v/v, 5 …

An efficient, rapid oxidation of various aliphatic amines to oximes using m-CPBA as an
oxidant in ethyl acetate is described. High conversion (100%) with> 90% oxime selectivity is …

Unusual regio-and chemoselective oxidation of aromatic amines hindered with ortho
substituents (except-NH2,-NHCH3, and-OH) to the corresponding nitro compounds is …

Limited studies have been reported due to the difficulty of synthesizing multifunctional
catalysts to realize the redox reaction path cycle. Herein, two multifunctional Ru-containing …