Recent advances in the catalytic N-methylation and N-trideuteromethylation reactions using methanol and deuterated methanol
N-methylamine functionalities are valuable motifs, which play vital roles in the properties
and activities of essential fine and bulk chemicals including molecules used in life science …
and activities of essential fine and bulk chemicals including molecules used in life science …
Recent advances in sustainable organic transformations using methanol: expanding the scope of hydrogen-borrowing catalysis
The present review focuses on recent progress achieved from 2017 to March 2021 using
methanol as a C1-alkylating agent. A series of novel metal-catalyzed hydrogen-borrowing …
methanol as a C1-alkylating agent. A series of novel metal-catalyzed hydrogen-borrowing …
Multi-Functionality of Methanol in Sustainable Catalysis: Beyond Methanol Economy
Methanol is a fundamental feedstock and is widely used in the chemical and petroleum
industries. It can serve as a C1 source to make a variety of C–C and C–N bond formation …
industries. It can serve as a C1 source to make a variety of C–C and C–N bond formation …
Iridium supported on porous polypyridine-oxadiazole as high-activity and recyclable catalyst for the borrowing hydrogen reaction
J Li, A Mao, W Yao, H Zhu, D Wang - Green Chemistry, 2022 - pubs.rsc.org
Homogenization of heterogeneous catalysts is a valuable and interesting research topic.
Porous polypyridine-oxadiazole (PPO), as not only a carrier but also a ligand, was designed …
Porous polypyridine-oxadiazole (PPO), as not only a carrier but also a ligand, was designed …
Methanol as a greener C1 synthon under non-noble transition metal-catalyzed conditions
The exploration of methanol as a safe, easily accessible as well as environmentally benign
C1 synthon has captivated gigantic attention worldwide. It has surfaced as an increasingly …
C1 synthon has captivated gigantic attention worldwide. It has surfaced as an increasingly …
Monoselective N-Methylation of Amides, Indoles, and Related Structures Using Quaternary Ammonium Salts as Solid Methylating Agents
J Templ, E Gjata, F Getzner, M Schnürch - Organic Letters, 2022 - ACS Publications
We herein report the use of phenyl trimethylammonium iodide (PhMe3NI) as a safe,
nontoxic, and easy-to-handle reagent for an absolutely monoselective N-methylation of …
nontoxic, and easy-to-handle reagent for an absolutely monoselective N-methylation of …
Porous cross-linked polymer copper and iridium catalyzed the synthesis of quinoxalines and functionalized ketones under solvent-free conditions
J Li, M Yu, ZC Duan, H Zhu, W Yao… - Materials Chemistry …, 2021 - pubs.rsc.org
The development of highly active and efficient ligands is recognized to be crucial for the
catalytic applications of coordination polymers under specific conditions, such as solvent …
catalytic applications of coordination polymers under specific conditions, such as solvent …
Bicyclic (alkyl)(amino) carbene (BICAAC) in a dual role: activation of primary amides and CO 2 towards catalytic N-methylation
Herein, we report the first catalytic methylation of primary amides using CO2 as a C1 source.
A bicyclic (alkyl)(amino) carbene (BICAAC) exhibits dual role by activating both primary …
A bicyclic (alkyl)(amino) carbene (BICAAC) exhibits dual role by activating both primary …
Peroxide-mediated site-specific C–H methylation of imidazo [1, 2-a] pyridines and quinoxalin-2 (1 H)-ones under metal-free conditions
S Jin, H Yao, S Lin, X You, Y Yang… - Organic & Biomolecular …, 2020 - pubs.rsc.org
An effective approach to realize the direct methylation of imidazo [1, 2-a] pyridines and
quinoxalin-2 (1H)-ones with peroxides under metal-free conditions is described. In this …
quinoxalin-2 (1H)-ones with peroxides under metal-free conditions is described. In this …
Reforming of ethanol to hydrogen and acetic acid catalyzed by pincer-ruthenium complexes
Ethanol is feed-agnostic and is hence currently one of the most preferred renewable
resources for manufacturing essential industrial commodities globally. Herein, we present …
resources for manufacturing essential industrial commodities globally. Herein, we present …