Molecular main group metal hydrides
This review serves to document advances in the synthesis, versatile bonding, and reactivity
of molecular main group metal hydrides within Groups 1, 2, and 12–16. Particular attention …
of molecular main group metal hydrides within Groups 1, 2, and 12–16. Particular attention …
Hydrostibination
A rigid naphthalenediamine framework has been used to prepare antimony hydrides that
feature LUMO shapes and energies similar to those found in secondary boranes. By …
feature LUMO shapes and energies similar to those found in secondary boranes. By …
Persistent Antimony‐and Bismuth‐Centered Radicals in Solution
S Ishida, F Hirakawa, K Furukawa… - Angewandte Chemie …, 2014 - Wiley Online Library
Stibinyl and bismuthinyl radicals are recognized as representative intermediates of antimony
and bismuth compounds, but still elusive in the condensed phase. We successfully …
and bismuth compounds, but still elusive in the condensed phase. We successfully …
Different Products of the Reduction of (N),C,N‐Chelated Antimony(III) Compounds: Competitive Formation of Monomeric Stibinidenes versus 1H‐2,1 …
I Vránová, M Alonso, R Jambor… - … A European Journal, 2017 - Wiley Online Library
The reduction of N, C, N‐chelated antimony (III) chlorides [C6H3‐2, 6‐(CH= NR) 2] SbCl2
(R= Ph (1), tBu (2), Dip (3); Dip= 2, 6‐iPr2C6H3) with an appropriate amount of KC8 or Li …
(R= Ph (1), tBu (2), Dip (3); Dip= 2, 6‐iPr2C6H3) with an appropriate amount of KC8 or Li …
Synthesis of heteroleptic gallium-substituted antimony hydrides by stepwise β-H elimination
Heteroleptic stibanes Cp*(R) SbCl (R= Dip 1, N (SiMe3) 22, OB (NDipCH) 23; Cp*= C5Me5;
Dip= 2, 6-i-Pr2-C6H3) react with monovalent gallanediyl LGa (L= HC [C (Me) N (Dip)] 2) with …
Dip= 2, 6-i-Pr2-C6H3) react with monovalent gallanediyl LGa (L= HC [C (Me) N (Dip)] 2) with …
Stibine as a reagent in molecular chemistry-targeted synthesis of primary and secondary stibanyl-gallanes and their lighter homologues
S Schneider, S Ivlev, C von Haenisch - Chemical Communications, 2021 - pubs.rsc.org
The reactions of SbH3 with one or two equivalents of (Dipp2NacNac) Ga (Dipp2NacNac=
HC {C (Me) N (Dipp)} 2; Dipp= 2, 6-iPr2C6H3) yield the primary and secondary stibanes …
HC {C (Me) N (Dipp)} 2; Dipp= 2, 6-iPr2C6H3) yield the primary and secondary stibanes …
A study of di (amino) stibines with terminal Sb (iii) hydrogen-ligands by X-ray-and neutron-diffraction
RJ Schwamm, AJ Edwards, CM Fitchett… - Dalton Transactions, 2019 - pubs.rsc.org
The bis (amidodimethyl) disiloxane ligands [O {SiMe2NR} 2] 2−(R= 2, 6-Me2C6H3 (Ar′)
and 2, 6-iPr2C6H3 (Ar), abbreviated [NONR] 2−, are a stable support for Sb (III) complexes …
and 2, 6-iPr2C6H3 (Ar), abbreviated [NONR] 2−, are a stable support for Sb (III) complexes …
Synthesis and structural study on organoantimony (III) and organobismuth (III) hydroxides containing an NCN pincer type ligand
A Fridrichová, T Svoboda, R Jambor… - …, 2009 - ACS Publications
The reactions of the dimeric organoantimony (III) oxide [LSbO] 2 (3), containing the NCN
chelating ligand L (L= C6H3-2, 6-(CH2NMe2) 2) with trifluoroacetic acid and …
chelating ligand L (L= C6H3-2, 6-(CH2NMe2) 2) with trifluoroacetic acid and …
Structural Characterization of Et4Sb2 and Et4Bi2
A Kuczkowski, S Heimann, A Weber, S Schulz… - …, 2011 - ACS Publications
The solid-state structures of Et4Sb2 (1) and Et4Bi2 (2) were determined by single-crystal X-
ray diffraction. Single crystals of 1 and 2 were grown in a closed quartz glass capillary under …
ray diffraction. Single crystals of 1 and 2 were grown in a closed quartz glass capillary under …
Structure and Reactivity of 1, 8-Bis (naphthalenediyl) dipnictanes
K Dzialkowski, A Gehlhaar, C Wölper, AA Auer… - …, 2019 - ACS Publications
Syntheses and solid-state structures of diarsane Naph2As2 (Naph= 1, 8-naphthalenediyl, 1)
and (Naph) 5Sb4Cl2 3 are reported and the σ-donor capacity of Naph2E2 (E= As 1, Sb 2) …
and (Naph) 5Sb4Cl2 3 are reported and the σ-donor capacity of Naph2E2 (E= As 1, Sb 2) …