Visible-Light-Activated Heteroaryl Azoswitches: Toward a More Colorful Future

T Dang, ZY Zhang, T Li - Journal of the American Chemical …, 2024 - ACS Publications
Azobenzenes (Ph-N═ N-Ph) are known as the most widely studied molecular
photoswitches, and the recent rise of azoheteroarenes (Het-N═ N-Ph or Het-N═ N-Het) …

Recent progress in the development of molecular-scale electronics based on photoswitchable molecules

X Huang, T Li - Journal of Materials Chemistry C, 2020 - pubs.rsc.org
Molecular electronic devices with tunable conductance states show great potential in
building memories and logic components for next-generation circuits. In recent years …

Photocontrolled energy storage in azobispyrazoles with exceptionally large light penetration depths

A Gonzalez, M Odaybat, M Le… - Journal of the …, 2022 - ACS Publications
Azobispyrazole, 4pzMe-5pzH, derivatives with small terminal substituents (Me, Et, i-Pr, and n-
Pr) are reported to undergo facile reversible photoswitching in condensed phases at room …

Arylazopyrazoles for long-term thermal energy storage and optically triggered heat release below 0° C

MA Gerkman, RSL Gibson, J Calbo, Y Shi… - Journal of the …, 2020 - ACS Publications
Arylazopyrazole derivatives based on four core structures (4pzMe, 3pzH, 4pzH, and 4pzH-
F2) and functionalized with a dodecanoate group were demonstrated to store thermal …

Photochemical phase transitions enable coharvesting of photon energy and ambient heat for energetic molecular solar thermal batteries that upgrade thermal energy

ZY Zhang, Y He, Z Wang, J Xu, M Xie… - Journal of the …, 2020 - ACS Publications
Discovering physicochemical principles for simultaneous harvesting of multiform energy
from the environment will advance current sustainable energy technologies. Here we …

[HTML][HTML] Photoswitchable phase change materials for unconventional thermal energy storage and upgrade

S Wu, T Li, ZY Zhang, T Li, R Wang - Matter, 2021 - cell.com
Conventional thermophysical latent heat storage based on solid-liquid phase change
materials (PCMs) has been suffering three long-standing bottlenecks—ie, relatively low …

Optically-controlled variable-temperature storage and upgrade of thermal energy by photoswitchable phase change materials

S Wu, ZY Zhang, T Li, R Wang, T Li - ACS Materials Letters, 2023 - ACS Publications
Phase change materials (PCMs) show great promise for thermal energy storage and thermal
management. However, some critical challenges remain due to the difficulty in tuning solid …

Visible-light-induced reversible photochemical crystal–liquid transitions of azo-switches for smart and robust adhesives

X Huang, Z Shangguan, ZY Zhang, C Yu… - Chemistry of …, 2022 - ACS Publications
Photochemical crystal↔ liquid transitions (PCLTs) are interesting phenomena that couple
reversible photochemical transformations with thermophysical phase transitions. A potential …

Azobispyrazole family as photoswitches combining (near‐) quantitative bidirectional isomerization and widely tunable thermal half‐lives from hours to years

Y He, Z Shangguan, ZY Zhang, M Xie… - Angewandte Chemie …, 2021 - Wiley Online Library
Azobenzenes are classical molecular photoswitches that have been widely used. In recent
endeavors of molecular design, replacing one or both phenyl rings with heteroaromatic rings …

[HTML][HTML] A rechargeable molecular solar thermal system below 0° C

Z Shangguan, W Sun, ZY Zhang, D Fang, Z Wang… - Chemical …, 2022 - pubs.rsc.org
An optimal temperature is crucial for a broad range of applications, from chemical
transformations, electronics, and human comfort, to energy production and our whole planet …