Interaction of PtF6 vapor with a comparable molar quantity of Xe gas, at≈ 20° C, gives a
sticky, red-tinged yellow solid of composition Xe (PtF6) x, with 1≤ x≤ 2, X-ray powder …

With the aim of gauging their potential as conducting or superconducting materials, we
examine the crystal structures and magnetic properties of the roughly one hundred binary …

The review describes the syntheses of metal salts with weakly interacting anions (AlCl4−,
AsF6−, SbF6−) in the poorly coordinating solvent SO2. The metal centers in the resulting …

Properties of lead difluoride are considered. Phase equilibria in PbF2–MFn systems (n= 1–
5) and data on compounds and solid solutions formed in these systems are analysed. The …

Gold at∼ 20° C with F2 in anhydrous hydrogen fluoride (aHF) acidified with SbF5 dissolves
to a red solution from which orange AuII (SbF6) 2 crystallizes on removal of volatiles. Au …

Hexakis (carbonyl) iron (II) undecafluorodiantimonate (V),[Fe (CO) 6][Sb2F11] 2, is
conveniently prepared by the oxidative carbonylation of Fe (CO) 5 with XeF2 as external …

Homoleptic σ-bonded metal carbonyl cations (σ-carbonyls) and their derivatives have grown
in recent years into a large subgroup of mononuclear metal carbonyl complexes. They are at …

The ability of binary fluorides (MF x, x= 1-7) to donate fluoride ions to the Lewis acids AsF 5
and SbF 5, ie, the synthesis and characterization of solids with emphasis on structural data …

Рассмотрены свойства дифторида свинца. Проанализированы данные о фазовых
равновесиях в системах PbF 2-MF n (n= 1-5), об образующихся в них соединениях и …

The salts [M (CO) 4][Sb2F11] 2, M= Pd, Pt, are prepared by reductive carbonylation of Pd [Pd
(SO3F) 6], Pt (SO3F) 4 or PtF6 in liquid SbF5, or HF− SbF5. The resulting moisture-sensitive …