Recent Developments in the Ring‐Chain Tautomerism of 1, 3‐Heterocycles

L Lázár, F Fülöp - European Journal of Organic Chemistry, 2003 - Wiley Online Library
Some important results from the past seven years on the ring‐chain tautomerism of 1, 3‐
heterocycles are reviewed, including substituent effects on the tautomeric equilibria and …

Synthesis, characterization, and structure determination of bis-oxazolidine complexes of rhenium

RA Pohorenec, WW Brennessel… - New Journal of Chemistry, 2023 - pubs.rsc.org
A tetradentate fused bis-oxazolidine ligand (FOX) is used to coordinate to rhenium carbonyl.
The ligand binds in a κ3-NNN fashion to a Re (CO) 3+ fragment, giving an octahedral …

Synthesis and stereochemistry of some 1, 3-oxazolidine systems based on TRIS (α, α, α-trimethylolaminomethane) and related aminopolyols skeleton. Part 2: 1-aza-3 …

M Darabantu, G Plé, C Maiereanu, I Silaghi-Dumitrescu… - Tetrahedron, 2000 - Elsevier
The reaction of TRIS with equivalent amounts of two carbonyl compounds is shown to afford,
diastereoselectively, the title compounds. The results are discussed as a synthetic strategy …

Ring-chain tautomerism and other versatile behaviour of 1, 4-diimino-and 1, 2-phenylene derivatives of some C-substituted serinols

C Maiereanu, M Darabantu, G Plé, C Berghian… - Tetrahedron, 2002 - Elsevier
The behaviour of the title compounds, obtained from terephthaldicarboxaldehyde or 1, 2-
phthaldicarboxaldehyde and certain (non) chiral C-substituted serinols is discussed in terms …

Serine and Threonine Schiff Base Esters React with β-Anomeric Peracetates in the Presence of BF3·Et2O to Produce β-Glycosides

CM Keyari, R Polt - Journal of Carbohydrate Chemistry, 2010 - Taylor & Francis
Improved procedures are reported for the glycosylation of L-serine and L-threonine utilizing
activated Schiff base glycosyl acceptors, which are less expensive and more efficient …

An overview of highly optically pure chloramphenicol bases: applications and modifications

K Yang, H Fang, J Gong, L Su… - Mini Reviews in Medicinal …, 2009 - benthamdirect.com
Chloramphenicol (CAP) is a widely used broad-spectrum antibiotic. As the precursor of CAP,
chloramphenicol bases are stereochemically pure agents and could be used as resolution …

Serinolic amino-s-triazines: iterative synthesis and rotational stereochemistry phenomena as N-substituted derivatives of 2-aminopropane-1, 3-diols

M Pintea, M Fazekas, P Lameiras, I Cadis, C Berghian… - Tetrahedron, 2008 - Elsevier
The iterative synthesis of 2, 4, 6-triamino-s-triazines (melamines), precursors and dendritic
structures, by amination of cyanuric chloride with C-1 versus C-2-substituted 2 …

Five-component equilibria of ring-chain tautomeric mixtures derived from 2-amino-1-phenyl-1, 3-propanediol diastereomers

T Martinek, L Lázár, F Fülöp, FG Riddell - Tetrahedron, 1998 - Elsevier
In the reactions of (1R∗, 2S∗)-or (1S, 2S)-2-amino-1-phenyl-1, 3-propanediol with aromatic
aldehydes, five-component ring-chain tautomeric mixtures were formed, involving C-2 …

3, 7‐Dioxa‐1‐azabicyclo [3.3. 0] octanes Substituted at the C‐5 Position− From Local to Global Stereochemistry

M Darabantu, C Maiereanu… - European Journal of …, 2004 - Wiley Online Library
Multiple approaches are described for the elucidation of the stereochemistry in solution
(high‐resolution NMR spectroscopy) and in the solid state (X‐ray diffractometry) that are …

Serinolic Amino‐s‐triazines: Iterative Synthesis of N‐Substituted Amino‐1,3‐dioxane Derivatives from l‐(p‐Nitrophenyl)serinols and Rotational Stereochemistry …

M Fazekas, M Pintea, P Lameiras, A Lesur, C Berghian… - 2008 - Wiley Online Library
We report the first iterative and chemioselective approach towards the synthesis of highly
elaborated N‐substituted 2, 4, 6‐triamino‐s‐triazines (melamines) and precursors, by …