Trivalent europium–a scarce case in intermetallics
S Engel, ECJ Gießelmann, R Pöttgen… - Reviews in Inorganic …, 2023 - degruyter.com
In most intermetallic europium compounds, the Eu atoms exhibit a divalent oxidation state
with a high effective magnetic moment since Eu2+ is isoelectronic with Gd3+. Trivalent …
with a high effective magnetic moment since Eu2+ is isoelectronic with Gd3+. Trivalent …
Structural Characterization of Intermetallic Compounds by 27Al Solid State NMR Spectroscopy
Conspectus Intermetallic compounds are of broad interest for solid state chemists,
condensed matter physicists, and material scientists due to their intriguing crystal chemistry …
condensed matter physicists, and material scientists due to their intriguing crystal chemistry …
Anisotropic hybridization in CeRhSn
The optical conductivity σ (ω, T) of CeRhSn was studied by broadband infrared
spectroscopy. Temperature-dependent spectral weight transfer occurs over high energy (0.8 …
spectroscopy. Temperature-dependent spectral weight transfer occurs over high energy (0.8 …
[HTML][HTML] Bonding properties of molecular cerium oxides tuned by the 4f-block from ab initio perspective
Probing chemical bonding in molecules containing lanthanide elements is of theoretical
interest, yet it is computationally challenging because of the large valence space, relativistic …
interest, yet it is computationally challenging because of the large valence space, relativistic …
[HTML][HTML] Structure and bonding in TiNiSi type LaMgSnH intermetallic hydride
The work was aimed on reaching a better understanding of the effect of magnesium as a
component of the hydride-forming LaMgSn intermetallic compound crystallising with the …
component of the hydride-forming LaMgSn intermetallic compound crystallising with the …
Synthesis, magnetic and NMR spectroscopic properties of the MAl 5 Pt 3 series (M= Ca, Y, La–Nd, Sm–Er)
S Engel, ECJ Gießelmann, L Schumacher… - Dalton …, 2024 - pubs.rsc.org
Following recent investigation in the ternary system Sr–Al–Pt led to the discovery of SrAl5Pt3
which crystallizes in the orthorhombic YNi5Si3 type (Pnma) structure. Interestingly, only two …
which crystallizes in the orthorhombic YNi5Si3 type (Pnma) structure. Interestingly, only two …
Interplay between Kondo and magnetic interactions in Pr0. 75Gd0. 25ScGeH
Combined experimental and density functional theory (DFT) study of Pr 0.75 Gd 0.25 ScGe
and its hydride (Pr 0.75 Gd 0.25 ScGeH) reveals intricacies of composition-structure …
and its hydride (Pr 0.75 Gd 0.25 ScGeH) reveals intricacies of composition-structure …
Crystal, Magnetic Structures, and Bonding Interactions in the TiNiSi-Type Hydride CeMgSnH: Experimental and Computational Studies
By combining experimental and computational studies, the orthorhombic stannide CeMgSn
with a TiNiSi-type structure has been characterized as a potential hydrogen storage …
with a TiNiSi-type structure has been characterized as a potential hydrogen storage …
Magnetic and magnetocaloric properties of the equiatomic europium intermetallics EuAgZn, EuAgCd, EuPtZn and EuAuCd
S Klenner, Z Zhang, R Poettgen, L Li - Intermetallics, 2020 - Elsevier
The europium-based intermetallic compounds EuAgZn, EuAgCd, EuPtZn and EuAuCd were
synthesized and their magnetic properties and magnetocaloric performances were …
synthesized and their magnetic properties and magnetocaloric performances were …
Origins of magnetic memory and strong exchange bias bordering magnetic compensation in mixed-lanthanide systems
Unexpected physical phenomena resulting from the seemingly inconsequential substitutions
of chemically similar lanthanide elements in the Pr 1− x Gd x ScGe system are exploited to …
of chemically similar lanthanide elements in the Pr 1− x Gd x ScGe system are exploited to …