The precise control of the regioselectivity in the transition metal‐catalyzed migratory
hydrofunctionalization of alkenes remains a big challenge. With a transient ketimine …

The successful realization of gold‐catalyzed chain‐walking reactions, facilitated by ligand‐
enabled Au (I)/Au (III) redox catalysis, has been reported for the first time. This breakthrough …

As a general method for the synthesis of alcohols, the direct oxygenation of alkenes is
difficult to afford linear alcohols. Herein, we communicate the remote hydro-oxygenation of …

A general and broadly applicable cobalt-catalyzed multicomponent 1, 2-perfluoroalkylation
carbonylation of alkenes has been developed. This protocol allows the synthesis of β …

Novel strategy for acid chlorides formation that do not use carboxylic acids is particularly
attractive in chemical synthesis but remains challenging. Herein, we reported the …

While Mn-catalyzed (de) hydrogenation of carbonyl derivatives has been well established,
the reactivity of Mn hydrides with olefins remains very rare. Herein, we report a Mn (I) pincer …

A tungsten-catalyzed hydroboration of unactivated alkenes at distal C (sp3)–H bonds aided
by native directing groups is described herein. The method is characterized by its simplicity …

The effects of Lewis basic phosphoramides on the aggregate structure of t-BuLi have been
investigated in detail by NMR and DFT methods. It was determined that …

The control of regioselectivity in Heck-type reaction of unactivated alkenes represents a
longstanding challenge due to several detachable hydrogens in β–H elimination step, which …

The installation of deuterium atoms at distal C (sp3)–H bonds is a longstanding synthetic
challenge. Through the synergistic combination of chain-walking strategy and transfer …