Data analysis is central to understanding phenomena in host–guest chemistry. We describe
here recent developments in this field starting with the revelation that the popular Job plot …

C–N cross-coupling is one of the most valuable and widespread transformations in organic
synthesis. Largely dominated by Pd-and Cu-based catalytic systems, it has proven to be a …

Since the discovery of crown ethers, macrocycles have been recognized as powerful
platforms for supramolecular chemistry. Although their numbers and variations are now …

A fundamental understanding of anion binding by receptors is essential for managing salts
during energy, water, and food production. However, the limited understanding of solvent …

Recent mechanistic studies of dual photoredox/Ni-catalyzed, light-driven cross-coupling
reactions have found that the photocatalyst (PC) operates through either reductive …

The use of alcohol feedstock as a coupling partner in cross-coupling reactions offers an
extraordinary potential for the efficient synthesis of Csp3-rich complex molecular scaffolds …

Here we demonstrate a bioinspired system where light stimulus is used to trigger the
wavelength-dependent release and then reuptake of chloride ions in nonaqueous solutions …

Aqueous media are competitive environments in which to perform host–guest chemistry,
particularly when the guest is highly charged. While hydrophobic binding is a recognized …

Preorganization is a key concept in supramolecular chemistry. Preorganized receptors
enhance binding by minimizing the organization costs associated with adopting the …

This work demonstrates the dominance of a Ni (0/II/III) cycle for Ni‐photoredox amide
arylation, which contrasts with other Ni‐photoredox C‐heteroatom couplings that operate via …