Challenges and Future Perspectives in Photocatalysis: Conclusions from an Interdisciplinary Workshop

SB Beil, S Bonnet, C Casadevall, RJ Detz… - JACS Au, 2024 - ACS Publications
Photocatalysis is a versatile and rapidly developing field with applications spanning artificial
photosynthesis, photo-biocatalysis, photoredox catalysis in solution or supramolecular …

Copper nanoclusters: emerging photoredox catalysts for organic bond formations

A Sagadevan, K Murugesan, OM Bakr… - Chemical …, 2024 - pubs.rsc.org
Advancements in fine chemical synthesis and drug discovery continuously demand the
development of new and more efficient catalytic systems. In this regard, numerous transition …

Exploration on Metal-Catalytic Conversion of Sulfinyl Sulfones

Y Li, L Liu, D Shan, F Liang, S Wang, L Yu, JQ Liu… - ACS …, 2023 - ACS Publications
The utilization of sulfinyl sulfones in transition-metal-catalyzed synthetic chemistry has rarely
been investigated. Here we report the design and utilization of nickel-catalytic conversion of …

Red Light–Blue Light Chromoselective C(sp2)–X Bond Activation by Organic Helicenium-Based Photocatalysis

MM Hossain, AC Shaikh, R Kaur… - Journal of the American …, 2024 - ACS Publications
Chromoselective bond activation has been achieved in organic helicenium (n Pr-DMQA+)-
based photoredox catalysis. Consequently, control over chromoselective C (sp2)–X bond …

Photochemical Organocatalytic Synthesis of Thioethers from Aryl Chlorides and Alcohols

S Wu, THF Wong, P Righi… - Journal of the American …, 2024 - ACS Publications
Thioethers, often found in pharmaceuticals and natural compounds, typically involve metal
cross-coupling reactions, high temperatures, and the use of disagreeable thiols for their …

Sequential One-Pot (Het) arene Thioetherification and Amination with Nickel and Visible Light

J Düker, I Ghosh, B König - ACS Catalysis, 2023 - ACS Publications
The development of predictable methods to increase molecular complexity is of paramount
importance in modern organic chemistry, especially in the context of synthesizing …

C–heteroatom coupling with electron-rich aryls enabled by nickel catalysis and light

S Ni, R Halder, D Ahmadli, EJ Reijerse, J Cornella… - Nature Catalysis, 2024 - nature.com
Nickel photoredox catalysis has resulted in a rich development of transition-metal-catalysed
transformations for carbon–heteroatom bond formation. By harnessing light energy, the …

4D Catalysis Concept Enabled by Multilevel Data Collection and Machine Learning Analysis

AS Galushko, VP Ananikov - ACS Catalysis, 2023 - ACS Publications
The influence of catalysis on the development of modern science and industry cannot be
overestimated. Production of pharmaceutical substances and drugs, 1, 2 the oil industry, 3 …

C (sp 2)–S cross-coupling reactions with nickel, visible light, and mesoporous graphitic carbon nitride

M Nikitin, F Babawale, S Tastekin, M Antonietti… - Green …, 2024 - pubs.rsc.org
Cross-coupling reactions play a vital role in modern organic synthesis, enabling the
construction of necessary C–C or C–(het) atom bonds for synthetic transformations …

Ultrafast Photophysics of Ni (I)–Bipyridine Halide Complexes: Spanning the Marcus Normal and Inverted Regimes

E Sutcliffe, DA Cagan, RG Hadt - Journal of the American …, 2024 - ACS Publications
Owing to their light-harvesting properties, nickel–bipyridine (bpy) complexes have found
wide use in metallaphotoredox cross-coupling reactions. Key to these transformations are Ni …