The hallmark of nucleophilic phosphine catalysis is the initial nucleophilic addition of a
phosphine to an electrophilic starting material, producing a reactive zwitterionic …

Asymmetric phosphine catalysis showcasing remarkable progress over the past two
decades has emerged as a key synthetic platform for the creation of molecular frameworks …

Nucleophilic phosphine catalysis is a practical and powerful tool for the synthesis of various
heterocyclic compounds with the advantages of environmentally friendly, metal-free, and …

Over the past years, the metal‐catalyzed dearomative cycloaddition of 3‐nitroindoles and 2‐
nitrobenzofurans have emerged as a powerful protocol to construct chiral fused heterocyclic …

Chiral monophosphorus ligands are playing an important role for the recent advances in
asymmetric catalysis. This review summarizes the latest progress in various asymmetric …

Lu's [3+ 2] cycloaddition reaction has experienced explosive development due to its
versatile and powerful ability to access highly functionalized carbo-and heterocycles. After …

The first type II intramolecular [3+ 2] annulation of allenylsilane-ene has been achieved,
enabling diastereoselective and efficient construction of synthetically challenging bridged …

Phosphine‐catalyzed enantioselective annulation reactions involving ketimines are a
daunting synthetic challenge owing to the intrinsic low reactivity of ketimine substrates. A …

A novel phosphine‐catalyzed, highly enantioselective umpolung addition of trifluoromethyl
ketimines to Morita–Baylis–Hillman carbonates was developed and it provides facile access …

Intramolecular Morita–Baylis–Hillman and Rauhut–Currier reactions are important tools
which have constantly grown over several years. This review summarizes and highlights …