The synthesis of Janus-type layers, which possess front and back sides that consist of
different structures, remains a major challenge in the field of two-dimensional materials. In …

Zero thermal expansion materials are crucial for manufacturing high-precision devices, but
most of these materials discovered so far are inorganic. Organic zero thermal expansion …

Three sets of related lanthanide–mercury (II) cyanide coordination polymers were
synthesized by the reaction of LnCl3· x H2O (Ln= Ce, Nd, Eu, Gd, Tb, Dy, Ho, Tm, Yb, and …

The thermal expansion of eight compounds from the well-known AB (XCN) 4 family of
thiocyanate-and selenocyanate-bridged frameworks (A= Co, Zn, Cd; B= Cd, Hg; X= S, Se) …

Flat layers are usually considered as structurally rigid motifs in two-dimensional (2D)
materials. In this work, we demonstrate that a flat honeycomb-layer composed of distorted tri …

Zero thermal expansion materials are important for the practical applications due to their
shape stability as changing temperature. The reported concept of average atomic volume is …

Longitudinal zero thermal expansion (LZTE) alloys hold unique application potentials due to
their size stability along the longitudinal direction and thermal expansion compatibility inside …

抄録 We have investigated cyanide-based metal complexes, which were synthesized by
combining [M (CN) 4] 2-(M= Pt, Pd, Ni) or [MN (CN) 4] 2-(M= Mn, Re) with metal complex …