Chemi-and bioluminescence of cyclic peroxides

M Vacher, I Fdez. Galván, BW Ding, S Schramm… - Chemical …, 2018 - ACS Publications
Bioluminescence is a phenomenon that has fascinated mankind for centuries. Today the
phenomenon and its sibling, chemiluminescence, have impacted society with a number of …

[HTML][HTML] Advanced chemistry of dioxetane-based chemiluminescent substrates originating from bioluminescence

M Matsumoto - Journal of Photochemistry and Photobiology C …, 2004 - Elsevier
A class of high-energy molecules, the 1, 2-dioxetanes, have received a great deal of
attention because of their unique ability to decompose thermally into electronically excited …

The molecular basis of organic chemiluminescence

MC Cabello, FH Bartoloni, EL Bastos, WJ Baader - Biosensors, 2023 - mdpi.com
Bioluminescence (BL) and chemiluminescence (CL) are interesting and intriguing
phenomena that involve the emission of visible light as a consequence of chemical …

All eyes on visible‐light peroxyoxalate chemiluminescence read‐out systems

L Delafresnaye, FR Bloesser… - … A European Journal, 2020 - Wiley Online Library
Chemiluminescence (CL) reactions have been widely employed and explored over the past
50 years because they offer unique light emission upon a defined chemical stimulus. In this …

Molecular basis of the chemiluminescence mechanism of luminol

A Giussani, P Farahani… - … A European Journal, 2019 - Wiley Online Library
Light emission from luminol is probably one of the most popular chemiluminescence
reactions due to its use in forensic science, and has recently displayed promising …

Mechanistic insight into the chemiluminescent decomposition of firefly dioxetanone

L Yue, YJ Liu, WH Fang - Journal of the American Chemical …, 2012 - ACS Publications
The peroxide decomposition that generates the excited-state carbonyl compound is the key
step in most organic chemiluminescence, and chemically initiated electron exchange …

Conical intersection in chemiluminescence of cyclic peroxides

L Yue, YJ Liu - The Journal of Physical Chemistry Letters, 2022 - ACS Publications
Chemiluminescence (CL) utilizing chemiexcitation for energy transformation is one of the
most highly sensitive and useful analytical techniques. The chemiexcitation is a chemical …

DFT studies of interaction between O2 and Au clusters. The role of anionic surface Au atoms on Au clusters for catalyzed oxygenation

M Okumura, Y Kitagawa, M Haruta… - Chemical physics letters, 2001 - Elsevier
Density functional and ab initio molecular orbital (MO) calculations have been carried out for
the AuO, AuO2, AuO2−, and the Au13O2 clusters. The results show that the surface atoms of …

Mechanistic insights in charge-transfer-induced luminescence of 1, 2-dioxetanones with a substituent of low oxidation potential

H Isobe, Y Takano, M Okumura… - Journal of the …, 2005 - ACS Publications
We have investigated the decomposition pathway of dioxetanones 1c with a phenoxide
anion group by the B3LYP/6-31+ G (d) method together with the second-order …

[HTML][HTML] Understanding the complete bioluminescence cycle from a multiscale computational perspective: A review

YJ Liu - Journal of Photochemistry and Photobiology C …, 2022 - Elsevier
Bioluminescence (BL) is an amazing natural phenomenon whose visible light is produced
by living organisms. BL phenomenon is quite pervasive and has been observed in 17 phyla …