Catalytic strategies and mechanism analysis orbiting the center of critical intermediates in lignin depolymerization

C Zhang, X Shen, Y Jin, J Cheng, C Cai… - Chemical …, 2023 - ACS Publications
Lignin, as a precious resource given to mankind by nature with abundant functional aromatic
structures, has drawn much attention in the recent decade from academia to industry …

A unified view on catalytic conversion of biomass and waste plastics

K Lee, Y Jing, Y Wang, N Yan - Nature Reviews Chemistry, 2022 - nature.com
Originating from the desire to improve sustainability, producing fuels and chemicals from the
conversion of biomass and waste plastic has become an important research topic in the …

Anti-Markovnikov intermolecular hydroamination of alkenes and alkynes: a mechanistic view

J Escorihuela, A Lledós, G Ujaque - Chemical Reviews, 2023 - ACS Publications
Hydroamination, the addition of an N–H bond across a C–C multiple bond, is a reaction with
a great synthetic potential. Important advances have been made in the last decades …

Paving the way for lignin valorisation: recent advances in bioengineering, biorefining and catalysis

R Rinaldi, R Jastrzebski, MT Clough… - Angewandte Chemie …, 2016 - Wiley Online Library
Lignin is an abundant biopolymer with a high carbon content and high aromaticity. Despite
its potential as a raw material for the fuel and chemical industries, lignin remains the most …

Aromatic monomers by in situ conversion of reactive intermediates in the acid-catalyzed depolymerization of lignin

PJ Deuss, M Scott, F Tran, NJ Westwood… - Journal of the …, 2015 - ACS Publications
Conversion of lignin into well-defined aromatic chemicals is a highly attractive goal but is
often hampered by recondensation of the formed fragments, especially in acidolysis. Here …

Catalytic silylation of unactivated C–H bonds

C Cheng, JF Hartwig - Chemical Reviews, 2015 - ACS Publications
Methods for efficient, catalytic functionalization of unactivated C− H bonds with boron 1 and
silicon 2 reagents are valuable to the fields of synthetic chemistry and materials science …

Metal-catalyzed activation of ethers via C–O bond cleavage: a new strategy for molecular diversity

J Cornella, C Zarate, R Martin - Chemical Society Reviews, 2014 - pubs.rsc.org
In 1979, the seminal work of Wenkert set the standards for the utilization of aryl and vinyl
ethers as coupling partners via C–O bond-cleavage. Although the topic remained dormant …

Silylation of C–H bonds in aromatic heterocycles by an Earth-abundant metal catalyst

AA Toutov, WB Liu, KN Betz, A Fedorov, BM Stoltz… - Nature, 2015 - nature.com
Heteroaromatic compounds containing carbon–silicon (C–Si) bonds are of great interest in
the fields of organic electronics and photonics, drug discovery, nuclear medicine and …

Catalytic scissoring of lignin into aryl monomers

M Wang, F Wang - Advanced Materials, 2019 - Wiley Online Library
Lignin is an aromatic polymer, which is the biggest and most sustainable reservoir for
aromatics. The selective conversion of lignin polymers into aryl monomers is a promising …

Sustainable productions of organic acids and their derivatives from biomass via selective oxidative cleavage of C–C bond

M Wang, J Ma, H Liu, N Luo, Z Zhao, F Wang - ACS Catalysis, 2018 - ACS Publications
Biomass is renewable and the most abundant carbon resource, and it shows great potential
for sustainable production of chemicals in the future. With respect to limited fossil reserves …