Well-defined organometallics supported on high surface area oxides are promising
heterogeneous catalysts. An important design factor in these materials is how the metal …

The definition of the van der Waals crust as the spherical section between the atomic radius
and the van der Waals radius of an element is discussed and a survey of the application of …

The highly selective catalytic hydroformylation of alkenes to produce aldehydes is an
important reaction in the chemical industry. While the recycling of the currently used …

Annual Reports on NMR Spectroscopy, Volume 111 presents the latest release in a series
that has established itself as a premier resource for both specialists and non-specialists …

Two T‐shaped 14‐electron rhodium complexes 2 a and 2 b,“framed” and thus stabilized by
PNP pincer ligands have been synthesized. The bis (t‐butyl) phosphine derived PNPtBu …

σ-complexes of homoatomic E–E bonds are key intermediates in catalytically relevant
oxidative addition reactions, but are as yet unknown for the group 13 elements. Here, stable …

Zwei T‐förmige 14‐Elektronen‐Rhodiumkomplexe, 2 a und 2 b, wurden durch PNP‐Pincer
Liganden „eingerahmt “und somit stabilisiert. Der Bis (t‐butyl) phosphin‐PNP‐Komplex 2 a …

Complex {Ir [SiMe (o-C6H4SMe) 2](H)(PPh3)(THF)}[BArF4](1) has been shown to be an
effective catalyst in the hydrosilylation of aldehydes. Kinetic analysis of the catalysis …

1, 2, 3-Triazoles bearing additional functional groups have found applications as the ligands
in catalysis of a broad scope of reactions, synthesis of transition metals complexes for …

This contribution reveals the first synthesis, protonation reactions and skeletal
rearrangements of a series of [M (η 5-C 5 R 5)(η 2: η 2-bicyclo [3.2. 1] octa-2, 6-diene or 2, 6 …