Magnetic relaxation in single-ion magnets formed by less-studied lanthanide ions Ce (III), Nd (III), Gd (III), Ho (III), Tm (II/III) and Yb (III)

A Borah, R Murugavel - Coordination Chemistry Reviews, 2022 - Elsevier
Recent growth in the area of single-molecule magnets (SMMs) in general, and single-ion
magnets (SIMs) in particular, is due to the potential applications of this class of compounds …

Magnetic materials based on heterometallic Cr II/III–Ln III complexes

P Shukla, S Das, P Bag, A Dey - Inorganic Chemistry Frontiers, 2023 - pubs.rsc.org
Accommodating disparate spin centres within a single ensemble is a valuable synthetic
strategy to obtain interesting molecular magnetic materials. 3d–4f heterometallic complexes …

Family of Chiral ZnII–LnIII (Ln = Dy and Tb) Heterometallic Complexes Derived from the Amine–Phenol Ligand Showing Multifunctional Properties

HR Wen, JJ Hu, K Yang, JL Zhang, SJ Liu… - Inorganic …, 2020 - ACS Publications
A family of chiral 3d–4f heterometallic complexes, namely,[Zn2Ln (R, RL) 2 (H2O) 4](ClO4)
3)[Ln= Dy (1), Tb (3)],[Zn2Ln (S, SL) 2 (H2O) 4](ClO4) 3 [Ln= Dy (2), Tb (4)],[Zn2Ln2 (R, RL) …

A single-ion magnet building block strategy toward Dy 2 single-molecule magnets with enhanced magnetic performance

D Shao, PP Sahu, WJ Tang, YL Zhang, Y Zhou… - Dalton …, 2022 - pubs.rsc.org
A molecular dysprosium (III) complex [Dy (DClQ) 3 (H2O) 2](1) was used as a building unit
for the construction of lanthanide SMMs, leading to the isolation of two dinuclear Dy (III) …

Insights into the Spin Dynamics of Mononuclear Cerium (III) Single-Molecule Magnets

FA Mautner, F Bierbaumer, RC Fischer… - Inorganic …, 2022 - ACS Publications
Four novel CeIII mononuclear complexes of formulas [Ce (ntfa) 3 (MeOH) 2](1),[Ce (ntfa) 3
(5, 5′-Me2bipy)](2),[Ce (ntfa) 3 (terpy)](3), and [Ce (ntfa) 3 (bipy) 2](4), where ntfa= 4, 4, 4 …

3D isomorphous lanthanide coordination polymers displaying magnetic refrigeration, slow magnetic relaxation and tunable proton conduction

SP Bera, A Mondal, S Roy, B Dey, A Santra… - Dalton …, 2018 - pubs.rsc.org
Four new isostructural lanthanide-based three-dimensional (3D) coordination polymers
(CPs),{[Ln4 (OH) 4 (L) 2 (H2O) 8]· 4.6 H2O· 1.4 CH3CN} n (Ln3+= Gd3+ (1), Dy3+ (2), Ho3+ …

Combined experimental and theoretical studies on a series of mononuclear Ln III single-molecule magnets: dramatic influence of remote substitution on the magnetic …

K Pramanik, Z Jagličić, R Herchel, P Brandão… - Dalton …, 2023 - pubs.rsc.org
A series of LnIII complexes of general formula [Ln (H2L1) 2 (NO3) 2 (H2O)](NO3)(1–5)[Ln=
Dy (1), Tb (2) Ho (3), Er (4), and Yb (5)] and an analogous DyIII complex with ligand …

Field-induced SIM behaviour in early lanthanide (iii) organophosphates containing 18-crown-6

A Borah, S Dey, SK Gupta, G Rajaraman… - Dalton …, 2023 - pubs.rsc.org
Single-ion magnets (SIMs) have attracted wide attention in recent years. Despite
tremendous progress in late lanthanide SIMs, reports on early lanthanides exhibiting SIM …

Dinuclear lanthanide–lithium complexes based on fluorinated β-diketonate with acetal group: Magnetism and effect of crystal packing on mechanoluminescence

DN Bazhin, YS Kudyakova, AS Bogomyakov… - Inorganic Chemistry …, 2019 - pubs.rsc.org
The synthesis of novel dinuclear lanthanide complexes with formulas [(LnL3)(LiL)(MeOH)](1–
3) and [(LnL3)(LiL)(H2O)](4–6)(Ln= Eu (III), Tb (III), Dy (III)) based on functionalized lithium β …

LnIII (Ln = La, Gd, and Dy) Benzimidazolium Tricarboxylate Coordination Polymers with Hydrogen Bonding Modulated Magnetic Relaxation

GA Ramakant, N Ahmed, I Tarannum… - Crystal Growth & …, 2022 - ACS Publications
The novel LnIII {Ln= Dy (1-Dy), Gd (2-Gd), and La (3-La)} benzimidazolium tricarboxylate
coordination polymers have been synthesized, and their magnetic properties have been …