To each his own: isonitriles for all flavors. Functionalized isocyanides as valuable tools in organic synthesis

M Giustiniano, A Basso, V Mercalli… - Chemical Society …, 2017 - pubs.rsc.org
The term functionalized isocyanides refers to all those isocyanides in which a neighbouring
functional group can finely tune the reactivity of the isocyano group or can be exploited in …

Total synthesis of natural products using gold catalysis

S De, AK Dan, R Sahu, S Parida… - Chemistry–An Asian …, 2022 - Wiley Online Library
Gold catalysis is an extremely enthusiastic field of investigation in the catalysis area. The
development of alternative, highly inventive, precompetitive techniques based on gold …

Concise total synthesis of lundurines A–C enabled by gold catalysis and a homodienyl retro-ene/ene isomerization

MS Kirillova, ME Muratore, R Dorel… - Journal of the …, 2016 - ACS Publications
The total synthesis of lundurines A–C has been accomplished in racemic and enantiopure
forms in 11–13 and 12–14 steps, respectively, without protection/deprotection of functional …

Recent developments in sulfur-and selenium-catalyzed oxidative and isohypsic functionalization reactions of alkenes

A Breder, S Ortgies - Tetrahedron Letters, 2015 - Elsevier
This digest manuscript delineates recent developments in the context of sulfur-and selenium-
catalyzed oxidative and isohypsic functionalization reactions of simple alkenes. The …

Unified total synthesis of pyrroloazocine indole alkaloids sheds light on their biosynthetic relationship

FM Miloserdov, MS Kirillova, ME Muratore… - Journal of the …, 2018 - ACS Publications
The total synthesis of seven members of the lapidilectine and grandilodine family of
alkaloids has been accomplished in racemic and enantiopure form without protection …

Recent developments in the total synthesis of natural products using the Ugi multicomponent reactions as the key strategy

EL Larghi, ABJ Bracca, SO Simonetti… - Organic & Biomolecular …, 2024 - pubs.rsc.org
The total syntheses of selected natural products using different versions of the Ugi
multicomponent reaction is reviewed on a case-by-case basis. The revision covers the …

Multiple Roles of the Pyrimidyl Group in the Rhodium‐Catalyzed Regioselective Synthesis and Functionalization of Indole‐3‐carboxylic Acid Esters

H Jiang, S Gao, J Xu, X Wu, A Lin… - Advanced Synthesis & …, 2016 - Wiley Online Library
A regioselective synthesis of indole‐3‐carboxylic acid esters from anilines and diazo
compounds has been realized by making use of the pyrimidyl group‐assisted rhodium …

A Concise and Versatile Synthesis of Alkaloids from Kopsia tenuis: Total Synthesis of (±)‐Lundurine A and B

S Arai, M Nakajima, A Nishida - … Chemie International Edition, 2014 - Wiley Online Library
A total synthesis of (±)‐lundurines A and B is described. These natural products have a
unique hexacyclic skeleton which includes a cyclopropane‐fused indoline. A stereospecific …

Directing-group-assisted manganese-catalyzed cyclopropanation of indoles

PK Dutta, J Chauhan, MK Ravva, S Sen - Organic letters, 2019 - ACS Publications
The first manganese-catalyzed cyclopropanation of indoles is reported in moderate to
excellent yield with methyl-2-diazo-2-arylacetates. This new strategy involved acetyl …

Total synthesis of (±)-Grandilodine B

C Wang, Z Wang, X Xie, X Yao, G Li, L Zu - Organic letters, 2017 - ACS Publications
The first total synthesis of the opened-type Kopsia alkaloid grandilodine B is reported. Four
stereocenters of this alkaloid, three of them quaternary, are stereoselectively generated by a …