With the increasing demand for organosilicon compounds in organic synthesis as well as
material sciences, development of new methodologies that offer efficient entries into a …

Scaffold diversity is a key feature of a compound library and plays a pivotal role in its
success in biological screening. Therefore, it is highly desirable to develop efficient …

Organosilicon compounds act as a nucleophile upon activation by an appropriate base and
behave in a manner similar to main-group organometallic reagents. In the last decades …

Transition metal-catalyzed reactions of silacyclobutanes with a variety of π units have
attracted much attention and become one of the most straightforward and efficient …

The development of a straightforward strategy to obtain enantioenriched silicon‐stereogenic
benzosiloles remains a challenging yet appealing synthesis venture due to their potential …

Silaspiranes have attracted particular attention due to their chiral spiro‐silicon center, which
serves as an ideal carbon isostere and can endow spiro‐analogs with distinct properties …

A novel and unusual palladium‐catalyzed [4+ 2] annulation of cyclopropenes with
benzosilacyclobutanes is reported. This reaction occurred through chemoselective Si− C …

Silacycle is one of the most essential core frameworks in silicon-containing functional
molecules. However, the structural diversity of silacycles has been largely limited due to the …

Small-ring silacycles are important organosilane species in main-group chemistry and have
found numerous applications in organic synthesis. 3-Silaazetidine, a unique small silacycle …

A palladium–isocyanide complex opens the two four-membered rings of
benzocyclobutenone and silacyclobutane to merge them into an eight-membered ring …