Coordinatively unsaturated metal sites (open metal sites) in metal–organic frameworks: design and applications

Ü Kökçam-Demir, A Goldman, L Esrafili… - Chemical Society …, 2020 - pubs.rsc.org
Metal–organic frameworks (MOFs) can contain open metal sites (OMS) or coordinatively
unsaturated sites (CUS) or open coordination sites (OCS) when vacant Lewis acid sites on …

[HTML][HTML] Applications of metal–organic frameworks for green energy and environment: New advances in adsorptive gas separation, storage and removal

B Wang, LH Xie, X Wang, XM Liu, J Li, JR Li - Green Energy & Environment, 2018 - Elsevier
The separation of gas molecules with similar physicochemical properties is of high
importance but practically entails a substantial energy penalty in chemical industry …

Fabrication of carbon nanorods and graphene nanoribbons from a metal–organic framework

P Pachfule, D Shinde, M Majumder, Q Xu - Nature chemistry, 2016 - nature.com
One-and two-dimensional carbon nanomaterials are attracting considerable attention
because of their extraordinary electrical, mechanical and thermal properties, which could …

Series of M-MOF-184 (M = Mg, Co, Ni, Zn, Cu, Fe) Metal–Organic Frameworks for Catalysis Cycloaddition of CO2

YBN Tran, PTK Nguyen, QT Luong… - Inorganic …, 2020 - ACS Publications
In light of the chemical exploitation of CO2, new reusable materials for efficiently catalyzing
the cycloaddition of CO2 and epoxides under moderate conditions are needed. Herein, a …

Outlook and challenges for hydrogen storage in nanoporous materials

DP Broom, CJ Webb, KE Hurst, PA Parilla, T Gennett… - Applied Physics A, 2016 - Springer
Considerable progress has been made recently in the use of nanoporous materials for
hydrogen storage. In this article, the current status of the field and future challenges are …

Rational synthesis of mixed-metal microporous metal–organic frameworks with controlled composition using mechanochemistry

G Ayoub, B Karadeniz, AJ Howarth, OK Farha… - Chemistry of …, 2019 - ACS Publications
Mechanochemistry enables targeted, rapid synthesis of bimetallic metal–organic
frameworks (MOFs) with a controlled 1: 1 stoichiometric composition of metal nodes. In …

Solar powered adsorption desalination system employing CPO-27 (Ni)

M Ghazy, AA Askalany, EMM Ibrahim… - Journal of Energy …, 2022 - Elsevier
Adsorption-based desalination system (ADS) is an alternative technology to the traditional
water desalination systems as low-temperature sources can operate it. Also, ADSs use …

The application of MOFs for hydrogen storage

X Zhang, P Liu, Y Zhang - Inorganica Chimica Acta, 2023 - Elsevier
With the depletion of oil resources and the deterioration of the ecological environment,
finding and developing a safe, clean, and environmental-friendly energy source to meet the …

Metal-organic framework-based composites for biogas and natural gas uptake: An overview of adsorption and storage mechanisms of gaseous fuels

M Yusuf, R Kumar, MA Khan, MJ Ahmed… - Chemical Engineering …, 2023 - Elsevier
Biogas and natural gas are potential renewable energy sources. They primarily contain CH
4, H 2, CO 2, CO, C 2 H 6, C 3 H 8, H 2 S, N 2, and moisture. To be used as fuel, raw biogas …

Optimised room temperature, water-based synthesis of CPO-27-M metal–organic frameworks with high space-time yields

L Garzon-Tovar, A Carné-Sánchez… - Journal of Materials …, 2015 - pubs.rsc.org
The exceptional porosity of Metal–Organic Frameworks (MOFs) could be harnessed for
countless practical applications. However, one of the challenges currently precluding the …