Main group metal polymerisation catalysts

E Fazekas, PA Lowy, MA Rahman… - Chemical Society …, 2022 - pubs.rsc.org
With sustainability at the forefront of current polymerisation research, the typically earth-
abundant, inexpensive and low-toxicity main group metals are attractive candidates for …

Advances in non-metallocene olefin polymerization catalysis

VC Gibson, SK Spitzmesser - Chemical reviews, 2003 - ACS Publications
The field of olefin polymerization catalysis has experienced a phenomenal acceleration in
research activity over the past 5 years, with many academic and industrial research …

Cocatalysts for metal-catalyzed olefin polymerization: activators, activation processes, and structure− activity relationships

EYX Chen, TJ Marks - Chemical Reviews, 2000 - ACS Publications
One of the most exciting developments in the areas of catalysis, organometallic chemistry,
and polymer science in recent years has been the intense exploration and …

FI Catalysts for olefin polymerization A comprehensive treatment

H Makio, H Terao, A Iwashita, T Fujita - Chemical reviews, 2011 - ACS Publications
1.1. General Overview Polyolefinic materials, exemplified by polyethylenes (PEs),
polypropylenes (PPs), and ethylene/R-olefin amorphous copolymers, display many notable …

The search for new‐generation olefin polymerization catalysts: life beyond metallocenes

GJP Britovsek, VC Gibson… - Angewandte Chemie …, 1999 - Wiley Online Library
Even late transition metal complexes function as active and selective catalysts for α‐olefin
polymerization. The discovery of a highly active family of catalysts 1 based on iron, a metal …

Perspectives in catalytic applications of mesostructured materials

DT On, D Desplantier-Giscard, C Danumah… - Applied Catalysis A …, 2001 - Elsevier
This review paper deals with proven and potential applications of mesoporous molecular
sieves in catalysis. In addition to introduction and conclusion, the text is divided into two …

3 Advances in the coordination chemistry of amidinate and guanidinate ligands

FT Edelmann - Advances in organometallic chemistry, 2008 - books.google.com
The quest for alternatives to cyclopentadienyl-based ligands has led to a recent renaissance
of N-centered donor ligands in various fields of organometallic and coordination chemistry …

Catalytic polymerization and post polymerization catalysis fifty years after the discovery of Ziegler's catalysts

R Mülhaupt - Macromolecular Chemistry and Physics, 2003 - Wiley Online Library
During the 1920's Hermann Staudinger, who was awarded the Nobel prize in 1953,
introduced his revolutionary concept of high molecular weight macromolecules and …

Aluminum(III) Cations [(NHC) ⋅ AlMes2]+: Synthesis, Characterization, and Application in FLP‐Chemistry

L Werner, J Hagn, J Walpuski… - Angewandte Chemie …, 2023 - Wiley Online Library
The three‐coordinate aluminum cations ligated by N‐heterocyclic carbenes (NHCs)[(NHC)⋅
AlMes2]+[B (C6F5) 4]−(NHC= IMeMe 4, IiPrMe 5, IiPr 6, Mes= 2, 4, 6‐trimethylphenyl) were …

Reactions of Boron Amidinates with CO2 and CO and Other Small Molecules

MA Dureen, DW Stephan - Journal of the American Chemical …, 2010 - ACS Publications
Reaction of Piers' borane, HB (C6F5) 2, with either tert-butyl or isopropyl carbodiimide
cleanly affords the boron amidinates HC (RN) 2B (C6F5) 2 [R= i Pr (1), t Bu (2)]. These …