The use of transition metals to catalyse the addition of hydridoboranes to unsaturated
organic molecules was initially realised several decades ago. Although this area of …

Supramolecular catalysis is a rapidly expanding discipline which has benefited from the
development of both homogeneous catalysis and supramolecular chemistry. The properties …

Catalytic asymmetric synthesis has been one of the most active research areas in chemistry
(Nobel Prize in 2001). The development of efficient chiral catalysts plays a crucial role in …

Supramolecular catalysis—the assembly of catalyst species by harnessing multiple weak
intramolecular interactions—has, until recently, been dominated by enzyme-inspired …

Discovering efficient methods for gaining access to enantiomerically pure compounds in the
development of pharmaceuticals, agrochemicals, and flavors has been a great challenge for …

Catalytic enantioselective boron–hydride additions to 1, 3-enynes, which afford allenyl–B
(pin)(pin= pinacolato) products, are disclosed. Transformations are promoted by a readily …

In the past few years, supramolecular chemistry has led to new approaches in
homogeneous catalysis. While host-guest chemistry had already found applications in …

Chiral iminopyridine oxazoline (IPO) ligands were designed, synthesized and utilized for the
first cobalt-catalyzed highly regio-and enantioselective anti-Markovnikov hydroboration of 1 …

To accelerate the discovery of new or improved homogeneous catalysts, research groups in
industry and academia have embraced high throughput experimentation (HTE). Such …

The highly regio-and enantioselective iron-catalyzed anti-Markovnikov hydroboration of 1, 1-
disubstituted aryl alkenes is reported by using a novel chiral iminopyridine oxazoline (IPO) …