Controlling a chemical coupling reaction on a surface: tools and strategies for on-surface synthesis

S Clair, DG de Oteyza - Chemical reviews, 2019 - ACS Publications
On-surface synthesis is appearing as an extremely promising research field aimed at
creating new organic materials. A large number of chemical reactions have been …

Engineering quantum states and electronic landscapes through surface molecular nanoarchitectures

I Piquero-Zulaica, J Lobo-Checa, ZMA El-Fattah… - Reviews of Modern …, 2022 - APS
Surfaces are at the frontier of every known solid. They provide versatile supports for
functional nanostructures and mediate essential physicochemical processes. Intimately …

Hexatopic vertex-directed approach to vinylene-linked covalent organic frameworks with heteroporous topologies

Z Zhang, S Bi, F Meng, X Li, M Li, K Mou… - Journal of the …, 2023 - ACS Publications
AD 3 h-symmetric hexatopic monomer was first prepared by attaching the three-fold ditopic
moiety 2, 6-dimethylpyridine to the meta-positions of a phenyl ring. It was further condensed …

Planar π-extended cycloparaphenylenes featuring an all-armchair edge topology

F Xiang, S Maisel, S Beniwal, V Akhmetov… - Nature Chemistry, 2022 - nature.com
Abstract The [n] cycloparaphenylenes ([n] CPPs)—n para-linked phenylenes that form a
closed-loop—have attracted substantial attention due to their unique cyclic structure and …

Molecular bridge engineering for tuning quantum electronic transport and anisotropy in nanoporous graphene

C Moreno, X Diaz de Cerio… - Journal of the …, 2023 - ACS Publications
Recent advances on surface-assisted synthesis have demonstrated that arrays of
nanometer wide graphene nanoribbons can be laterally coupled with atomic precision to …

Tuning the diradical character of pentacene derivatives via non-benzenoid coupling motifs

T Wang, P Angulo-Portugal… - Journal of the …, 2023 - ACS Publications
The development of functional organic molecules requires structures of increasing size and
complexity, which are typically obtained by the covalent coupling of smaller building blocks …

Confined on-surface organic synthesis: Strategies and mechanisms

T Wang, J Zhu - Surface Science Reports, 2019 - Elsevier
On-surface synthesis has been one of the hottest research fields in surface science in the
last decade, owing to its great potential for bottom-up synthesis of functional molecules and …

Steering On-Surface Reactions by Kinetic and Thermodynamic Strategies

T Wang, Q Fan, J Zhu - The Journal of Physical Chemistry Letters, 2023 - ACS Publications
On-surface synthesis has emerged as a powerful tool to fabricate various functional low-
dimensional nanostructures with atomic precision, thus becoming a promising platform for …

On‐Surface Synthesis of Ethynylene‐Bridged Anthracene Polymers

A Sánchez‐Grande, B De la Torre, J Santos… - Angewandte …, 2019 - Wiley Online Library
Engineering low‐band‐gap π‐conjugated polymers is a growing area in basic and applied
research. The main synthetic challenge lies in the solubility of the starting materials, which …

Reassessing alkyne coupling reactions while studying the electronic properties of diverse pyrene linkages at surfaces

J Lawrence, MSG Mohammed, D Rey… - ACS …, 2021 - ACS Publications
The combination of alkyne and halogen functional groups in the same molecule allows for
the possibility of many different reactions when utilized in on-surface synthesis. Here, we …