Metallaheteroborane clusters containing group-16 elements as cluster constituents were
initially of interest solely for the synthesis of high-nuclearity clusters. However, owing to …

Transition metal triple‐decker complexes are an interesting class of sandwich complexes
that engrossed great attention due to their structures and properties. Over the decades …

Density functional theory (DFT) calculations using BP86 and B3LYP* methods have been
applied on a series of isoelectronic (CpFeCp') ML 3,(CpFeP 5) ML 3,(CpFeCp') FeCb and …

To establish a procedure for single-cage cluster expansion of open cage
dimetallaoctaboranes (12), we have investigated the chemistry of nido-[(Cp* M) 2B6H10](η5 …

A triple-decker complex of tungsten,[(Cp* W) 2 {μ-η6: η6-B4H4Co2 (CO) 5}(H) 2](1; Cp*= η5-
C5Me5), with a planar middle deck has been isolated by thermolysis of an in situ formed …

A series of lanthanide chalcogenides {[η5–1, 3-(Me3C) 2C5H3] 2Ln} 2 (μ-η2: η2-Te2)(Ln=
Ce 1, La 2),{[η5–1, 3-(Me3C) 2C5H3] 2Ln (THF)} 2 (μ-Se)(Ln= Ce 3, La 4), and {[η5–1, 3 …

Over time, cluster growth reactions for higher nuclearity clusters transformed into the main
goal in polyhedral metallaborane and metallaheteroborane chemistry. Metallaboranes and …

Earlier accounts of triple-decker complexes comprising main group elements and transition
metals in the middle-deck, motivated us to synthesize triple-decker complexes containing …

The feasibility of the formation of sandwich and multidecker complexes between O2
molecules and alkali/alkaline earth metals has been analyzed in the light of density …

Theoretical calculations using DFT/BP86 and DFT/B3LYP* methods have been applied on a
series of isoelectronic (CpFeCp') ML3,(CpFeP5) ML3,(CpFeCp') FeCb and (CpFeP5) FeCb …