This Review gives a comprehensive overview of the most topical weakly coordinating
anions (WCAs) and contains information on WCA design, stability, and applications. As an …

The chemistry of the p-block elements is a huge playground for fundamental and applied
work. With their bonding from electron deficient to hypercoordinate and formally hypervalent …

Although the β-diketonato1 I and β-enaminoketonato2, 3 II ligands are among the most
ubiquitous chelating systems in coordination chemistry, the isoelectronic β-diketiminato …

Synthetic routes to zinc β-diiminate complexes are reported. The synthesis of 11 β-diimine
[(BDI)-H] ligands, with varying N-aryl substituents and bridging structures, is described …

Three-coordinate organometallic complexes are rare, especially with the prototypical methyl
ligand. Using a hindered, rigid bidentate ligand (L), it is possible to create 12-electron …

Reaction of the β-diketiminato lithium salt Li (OEt2)[HC (CMeNAr) 2](Ar= 2, 6-i-Pr2C6H3)
with GeCl2⊙(dioxane) and SnCl2 in diethyl ether provided the monomeric complexes [HC …

Aluminum and gallium amidinate complexes,{RC (NR ') 2} MMe2 (R, R '= alkyl; M= Al, Ga),
react with the “cationic activators”[Ph3C][B (C6F5) 4] and B (C6F5) 3 to yield cationic Al and …

Boron and aluminum are lighter Group 13 elements, found in daily life commodities, and
considered environmentally benign. Nevertheless, they markedly differ in their elemental …

The base-free dimethyl scandium complex supported by the bulky β-diketiminato ligand
ArNC (t Bu) CHC (t Bu) NAr (Ar= 2, 6-i Pr2C6H3, 1) reacts with various equivalencies of the …

Synthesis, Characterization, and Applications of Group 13 Cationic Compounds | Chemical
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