Direct (hetero) arylation polymerization (DHAP) has recently been established as an
environmentally benign method for the preparation of conjugated polymers. This synthetic …

Palladium‐catalyzed amination reactions of aryl halides have undergone rapid development
in the last 12 years, largely driven by the implementation of new classes of ligands. Biaryl …

Over the past three decades, Pd-catalyzed cross-coupling reactions have become a
mainstay of organic synthesis. In particular, catalysts derived from biaryl monophosphines …

Dialkylbiaryl phosphines are a valuable class of ligand for Pd-catalyzed amination reactions
and have been applied in a range of contexts. This perspective attempts to aid the reader in …

Gold salts and complexes have emerged in the past few years as the most powerful
catalysts for electrophilic activation of alkynes toward a variety of nucleophiles under …

Despite the ubiquity of metallic gold (Au) in popular culture, its deployment in homogeneous
catalysis has only recently undergone widespread investigation. In the past decade, and …

Suzuki− Miyaura coupling reactions of aryl and heteroaryl halides with aryl-, heteroaryl-and
vinylboronic acids proceed in very good to excellent yield with the use of 2-(2 ', 6 ' …

A series of (NHC) Pd (R-allyl) Cl complexes [NHC: IPr= N, N '-bis (2, 6-diisopropylphenyl)
imidazol-2-ylidene, SIPr= N, N '-bis (2, 6-diisopropylphenyl)-4, 5-dihydroimidazol-2-ylidene; …

The use of N-heterocyclic carbenes as ligands for transition metals has increased
dramatically in the last few years, spurred on by their remarkable successes in the areas of …

Despite advances in the Suzuki–Miyaura cross-coupling process,[1] the need for an
operationally simple and general system remains. The minimum criteria for an optimum …