Transition Metal‐Catalyzed Hydroalkoxylation of Alkynes: An Overview

SK Nanda, R Mallik - Chemistry–A European Journal, 2021 - Wiley Online Library
Oxygen‐bearing motifs, mainly the congener heterocycles are ubiquitous due to their
presence in various natural products and bioactive scaffolds. Although in literature, several …

Catalytic alkyne/alkene-carbonyl metathesis: Towards the development of green organic synthesis

A Das, S Sarkar, B Chakraborty, A Kar… - Current Green …, 2020 - ingentaconnect.com
The construction of carbon-carbon bond through the metathesis reactions between
carbonyls and olefins or alkynes has attracted significant interest in organic chemistry due to …

Regio- and Chemoselective Synthesis of 3-(Dihydrofuran-3(2H)-ylidene)isobenzofuran-1(3H)-imines via Tandem Alkynyl Prins- and Intramolecular Oxycyclization …

S Shit, BK Behera, S Biswas… - The Journal of Organic …, 2023 - ACS Publications
A metal-free Lewis acid-initiated protocol for the synthesis of highly substituted 3-
(dihydrofuran-3 (2 H)-ylidene) isobenzofuran-1 (3 H)-imines from 2-(4-hydroxybut-1-yn-1-yl) …

Tunable Cascade Reactions of Alkynols with Alkynes under Combined Sc(OTf)3 and Rhodium Catalysis

DY Li, HJ Chen, PN Liu - Angewandte Chemie, 2016 - Wiley Online Library
Two tunable cascade reactions of alkynols and alkynes have been developed by combining
Sc (OTf) 3 and rhodium catalysis. In the absence of H2O, an endo‐cycloisomerization/C H …

Skeleton‐Reorganizing Coupling Reactions of Cycloheptatriene and Cycloalkenones with Amines

DW Ji, YC Hu, XT Min, H Liu, WS Zhang… - Angewandte Chemie …, 2023 - Wiley Online Library
Skeletal reorganization reactions have emerged as an intriguing tool for converting readily
available compounds into complicated molecules inaccessible by traditional methods …

Cascade Reaction of Alkynols and 7-Oxabenzonorbornadienes Involving Transient Hemiketal Group Directed C–H Activation and Synergistic RhIII/ScIII Catalysis

DY Li, LL Jiang, S Chen, ZL Huang, L Dang… - Organic …, 2016 - ACS Publications
As the first cascade C–H activation directed by a transient group, reaction of alkynols and 7-
oxabenzonorbornadienes has been achieved via synergistic rhodium and scandium …

Alkynyl Halo-Aza-Prins Annulative Couplings

JJ Hernandez, AP Lawrie… - The Journal of Organic …, 2023 - ACS Publications
This article is a comprehensive report describing our studies in the field of aza-alkynyl Prins
chemistry, comparing and contrasting the different reaction partners and reactivities …

Alkynyl Prins and Alkynyl Aza-Prins Annulations: Scope and Synthetic Applications

S Abdul-Rashed, C Holt, AJ Frontier - Synthesis, 2020 - thieme-connect.com
This review focuses on alkynyl Prins and alkynyl aza-Prins cyclization processes, which
involve intramolecular coupling of an alkyne with either an oxocarbenium or iminium …

Lewis acid promoted oxonium ion driven carboamination of alkynes for the synthesis of 4-alkoxy quinolines

SJ Gharpure, SK Nanda, PA Adate… - The Journal of Organic …, 2017 - ACS Publications
Lewis acid mediated multisegment coupling cascade is designed for the synthesis of
densely substituted 4-alkoxy quinolines via an oxonium ion triggered alkyne carboamination …

Enzyme‐and Ruthenium‐Catalyzed Enantioselective Transformation of α‐Allenic Alcohols into 2, 3‐Dihydrofurans

B Yang, C Zhu, Y Qiu, JE Bäckvall - Angewandte Chemie, 2016 - Wiley Online Library
An efficient one‐pot method for the enzyme‐and ruthenium‐catalyzed enantioselective
transformation of α‐allenic alcohols into 2, 3‐dihydrofurans has been developed. The …